Bis[μ-methyl­enebis(diphenyl­phosphine)]bis­[(5-nitro-1,10-phenanthroline)silver(I)] bis­(hexa­fluoridoanti­monate)

In the title compound, [Ag(2)(C(12)H(7)N(3)O(2))(2)(C(25)H(22)P(2))(2)](SbF(6))(2), the two Ag(I) atoms are bridged by the two methyl­enebis(diphenyl­phosphine) ligands and an eight-membered centrosymmetric metallacyclic ring is formed. The metal atom exhibits a distorted tetra­hedral coordination g...

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Detalles Bibliográficos
Autor principal: Yin, Gangqiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915175/
https://www.ncbi.nlm.nih.gov/pubmed/21200600
http://dx.doi.org/10.1107/S1600536807067013
Descripción
Sumario:In the title compound, [Ag(2)(C(12)H(7)N(3)O(2))(2)(C(25)H(22)P(2))(2)](SbF(6))(2), the two Ag(I) atoms are bridged by the two methyl­enebis(diphenyl­phosphine) ligands and an eight-membered centrosymmetric metallacyclic ring is formed. The metal atom exhibits a distorted tetra­hedral coordination geometry, coordinated by two P atoms of the bridging ligands and two N atoms of the chelating 5-nitro-1,10-phenanthroline ligand. The latter ligand shows minor disorder, adopting two orientations with site occupancy factors of 0.84 and 0.16.

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