2-(1H-Benzotriazol-1-yl)-1-(4-bromo­benzo­yl)ethyl 4-methyl­benzoate

In the mol­ecule of the title compound, C(23)H(18)BrN(3)O(3), the benzotriazole mean plane makes dihedral angles of 1.26 (1) and 87.39 (1)° with the tolyl and bromophenyl benzene rings, respectively, and the dihedral angle between the benzene rings is 87.27 (1)°. In the crystal structure, mol­ecules...

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Detalles Bibliográficos
Autores principales: Sun, Jiu-Long, Wang, Meng, Zhu, Ying-Jie, Li, Fang, Bi, Sai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915192/
https://www.ncbi.nlm.nih.gov/pubmed/21200686
http://dx.doi.org/10.1107/S1600536807062587
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author Sun, Jiu-Long
Wang, Meng
Zhu, Ying-Jie
Li, Fang
Bi, Sai
author_facet Sun, Jiu-Long
Wang, Meng
Zhu, Ying-Jie
Li, Fang
Bi, Sai
author_sort Sun, Jiu-Long
collection PubMed
description In the mol­ecule of the title compound, C(23)H(18)BrN(3)O(3), the benzotriazole mean plane makes dihedral angles of 1.26 (1) and 87.39 (1)° with the tolyl and bromophenyl benzene rings, respectively, and the dihedral angle between the benzene rings is 87.27 (1)°. In the crystal structure, mol­ecules are linked into chains along the a axis by C—H⋯O inter­molecular hydrogen bonds. The structure is further stabilized by C—H⋯π and π–π inter­actions, with a distance of 3.700 (1) Å between the centroids of the bromophenyl and benzotriazole benzene rings related by symmetry code (x, −1 + y, z).
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spelling pubmed-29151922010-12-30 2-(1H-Benzotriazol-1-yl)-1-(4-bromo­benzo­yl)ethyl 4-methyl­benzoate Sun, Jiu-Long Wang, Meng Zhu, Ying-Jie Li, Fang Bi, Sai Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(23)H(18)BrN(3)O(3), the benzotriazole mean plane makes dihedral angles of 1.26 (1) and 87.39 (1)° with the tolyl and bromophenyl benzene rings, respectively, and the dihedral angle between the benzene rings is 87.27 (1)°. In the crystal structure, mol­ecules are linked into chains along the a axis by C—H⋯O inter­molecular hydrogen bonds. The structure is further stabilized by C—H⋯π and π–π inter­actions, with a distance of 3.700 (1) Å between the centroids of the bromophenyl and benzotriazole benzene rings related by symmetry code (x, −1 + y, z). International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915192/ /pubmed/21200686 http://dx.doi.org/10.1107/S1600536807062587 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Sun, Jiu-Long
Wang, Meng
Zhu, Ying-Jie
Li, Fang
Bi, Sai
2-(1H-Benzotriazol-1-yl)-1-(4-bromo­benzo­yl)ethyl 4-methyl­benzoate
title 2-(1H-Benzotriazol-1-yl)-1-(4-bromo­benzo­yl)ethyl 4-methyl­benzoate
title_full 2-(1H-Benzotriazol-1-yl)-1-(4-bromo­benzo­yl)ethyl 4-methyl­benzoate
title_fullStr 2-(1H-Benzotriazol-1-yl)-1-(4-bromo­benzo­yl)ethyl 4-methyl­benzoate
title_full_unstemmed 2-(1H-Benzotriazol-1-yl)-1-(4-bromo­benzo­yl)ethyl 4-methyl­benzoate
title_short 2-(1H-Benzotriazol-1-yl)-1-(4-bromo­benzo­yl)ethyl 4-methyl­benzoate
title_sort 2-(1h-benzotriazol-1-yl)-1-(4-bromo­benzo­yl)ethyl 4-methyl­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915192/
https://www.ncbi.nlm.nih.gov/pubmed/21200686
http://dx.doi.org/10.1107/S1600536807062587
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