3,7,11,19,23,27-Hexaaza­tricyclo­[27.3.1.1(13,17)]tetra­triaconta-1(32),13,15,17(34),29(33),30-hexa­ene hexa­chloride tetra­hydrate

The title compound, C(28)H(52)N(6) (6+)·6Cl(−)·4H(2)O, is a dinucleating 28-membered centrosymmetric hexa­azamacrocyclic complex. The macrocyclic ligand adopts a chair-like conformation, with the crystallographic inversion center located in the macrocyclic cavity. The six chloride ions and four wate...

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Detalles Bibliográficos
Autores principales: Liu, Hai-Yan, Wei, Guo-Hua, Ma, Jian-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915196/
https://www.ncbi.nlm.nih.gov/pubmed/21200690
http://dx.doi.org/10.1107/S1600536807063064
Descripción
Sumario:The title compound, C(28)H(52)N(6) (6+)·6Cl(−)·4H(2)O, is a dinucleating 28-membered centrosymmetric hexa­azamacrocyclic complex. The macrocyclic ligand adopts a chair-like conformation, with the crystallographic inversion center located in the macrocyclic cavity. The six chloride ions and four water mol­ecules are situated symmetrically outside the macrocyclic cavity. The crystal structure is stabilized by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds.

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