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3,7,11,19,23,27-Hexaazatricyclo[27.3.1.1(13,17)]tetratriaconta-1(32),13,15,17(34),29(33),30-hexaene hexachloride tetrahydrate
The title compound, C(28)H(52)N(6) (6+)·6Cl(−)·4H(2)O, is a dinucleating 28-membered centrosymmetric hexaazamacrocyclic complex. The macrocyclic ligand adopts a chair-like conformation, with the crystallographic inversion center located in the macrocyclic cavity. The six chloride ions and four wate...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915196/ https://www.ncbi.nlm.nih.gov/pubmed/21200690 http://dx.doi.org/10.1107/S1600536807063064 |
| _version_ | 1782184883091668992 |
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| author | Liu, Hai-Yan Wei, Guo-Hua Ma, Jian-Fang |
| author_facet | Liu, Hai-Yan Wei, Guo-Hua Ma, Jian-Fang |
| author_sort | Liu, Hai-Yan |
| collection | PubMed |
| description | The title compound, C(28)H(52)N(6) (6+)·6Cl(−)·4H(2)O, is a dinucleating 28-membered centrosymmetric hexaazamacrocyclic complex. The macrocyclic ligand adopts a chair-like conformation, with the crystallographic inversion center located in the macrocyclic cavity. The six chloride ions and four water molecules are situated symmetrically outside the macrocyclic cavity. The crystal structure is stabilized by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds. |
| format | Text |
| id | pubmed-2915196 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29151962010-12-30 3,7,11,19,23,27-Hexaazatricyclo[27.3.1.1(13,17)]tetratriaconta-1(32),13,15,17(34),29(33),30-hexaene hexachloride tetrahydrate Liu, Hai-Yan Wei, Guo-Hua Ma, Jian-Fang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(52)N(6) (6+)·6Cl(−)·4H(2)O, is a dinucleating 28-membered centrosymmetric hexaazamacrocyclic complex. The macrocyclic ligand adopts a chair-like conformation, with the crystallographic inversion center located in the macrocyclic cavity. The six chloride ions and four water molecules are situated symmetrically outside the macrocyclic cavity. The crystal structure is stabilized by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915196/ /pubmed/21200690 http://dx.doi.org/10.1107/S1600536807063064 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Organic Papers Liu, Hai-Yan Wei, Guo-Hua Ma, Jian-Fang 3,7,11,19,23,27-Hexaazatricyclo[27.3.1.1(13,17)]tetratriaconta-1(32),13,15,17(34),29(33),30-hexaene hexachloride tetrahydrate |
| title | 3,7,11,19,23,27-Hexaazatricyclo[27.3.1.1(13,17)]tetratriaconta-1(32),13,15,17(34),29(33),30-hexaene hexachloride tetrahydrate |
| title_full | 3,7,11,19,23,27-Hexaazatricyclo[27.3.1.1(13,17)]tetratriaconta-1(32),13,15,17(34),29(33),30-hexaene hexachloride tetrahydrate |
| title_fullStr | 3,7,11,19,23,27-Hexaazatricyclo[27.3.1.1(13,17)]tetratriaconta-1(32),13,15,17(34),29(33),30-hexaene hexachloride tetrahydrate |
| title_full_unstemmed | 3,7,11,19,23,27-Hexaazatricyclo[27.3.1.1(13,17)]tetratriaconta-1(32),13,15,17(34),29(33),30-hexaene hexachloride tetrahydrate |
| title_short | 3,7,11,19,23,27-Hexaazatricyclo[27.3.1.1(13,17)]tetratriaconta-1(32),13,15,17(34),29(33),30-hexaene hexachloride tetrahydrate |
| title_sort | 3,7,11,19,23,27-hexaazatricyclo[27.3.1.1(13,17)]tetratriaconta-1(32),13,15,17(34),29(33),30-hexaene hexachloride tetrahydrate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915196/ https://www.ncbi.nlm.nih.gov/pubmed/21200690 http://dx.doi.org/10.1107/S1600536807063064 |
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