7-Bromo-3-ethyl-9-phenyl-2-tosyl­pyrrolo[3,4-b]quinoline

In the title compound, C(26)H(27)BrN(2)O(2)S, the pyrrolidine ring adopts a twist conformation, while the tetra­hydro­pyridine ring is in a half-chair conformation. The two rings are trans-fused. The dihedral angle between the phenyl ring and the sulfonyl-bound benzene ring is 22.83 (7)°. N—H⋯O hydr...

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Detalles Bibliográficos
Autores principales: Sudha, D., Chinnakali, K., Jayagobi, M., Raghunathan, R., Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915203/
https://www.ncbi.nlm.nih.gov/pubmed/21200698
http://dx.doi.org/10.1107/S1600536807063222
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author Sudha, D.
Chinnakali, K.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
author_facet Sudha, D.
Chinnakali, K.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
author_sort Sudha, D.
collection PubMed
description In the title compound, C(26)H(27)BrN(2)O(2)S, the pyrrolidine ring adopts a twist conformation, while the tetra­hydro­pyridine ring is in a half-chair conformation. The two rings are trans-fused. The dihedral angle between the phenyl ring and the sulfonyl-bound benzene ring is 22.83 (7)°. N—H⋯O hydrogen bonds link the mol­ecules into a chain along the b axis, and the chains are cross-linked into a three-dimensional network by a C—H⋯π inter­action and a weak π-π inter­action between the sulfonyl-bound benzene rings; the centroid–centroid distance is 3.6957 (8) Å.
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spelling pubmed-29152032010-12-30 7-Bromo-3-ethyl-9-phenyl-2-tosyl­pyrrolo[3,4-b]quinoline Sudha, D. Chinnakali, K. Jayagobi, M. Raghunathan, R. Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(27)BrN(2)O(2)S, the pyrrolidine ring adopts a twist conformation, while the tetra­hydro­pyridine ring is in a half-chair conformation. The two rings are trans-fused. The dihedral angle between the phenyl ring and the sulfonyl-bound benzene ring is 22.83 (7)°. N—H⋯O hydrogen bonds link the mol­ecules into a chain along the b axis, and the chains are cross-linked into a three-dimensional network by a C—H⋯π inter­action and a weak π-π inter­action between the sulfonyl-bound benzene rings; the centroid–centroid distance is 3.6957 (8) Å. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915203/ /pubmed/21200698 http://dx.doi.org/10.1107/S1600536807063222 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Sudha, D.
Chinnakali, K.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
7-Bromo-3-ethyl-9-phenyl-2-tosyl­pyrrolo[3,4-b]quinoline
title 7-Bromo-3-ethyl-9-phenyl-2-tosyl­pyrrolo[3,4-b]quinoline
title_full 7-Bromo-3-ethyl-9-phenyl-2-tosyl­pyrrolo[3,4-b]quinoline
title_fullStr 7-Bromo-3-ethyl-9-phenyl-2-tosyl­pyrrolo[3,4-b]quinoline
title_full_unstemmed 7-Bromo-3-ethyl-9-phenyl-2-tosyl­pyrrolo[3,4-b]quinoline
title_short 7-Bromo-3-ethyl-9-phenyl-2-tosyl­pyrrolo[3,4-b]quinoline
title_sort 7-bromo-3-ethyl-9-phenyl-2-tosyl­pyrrolo[3,4-b]quinoline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915203/
https://www.ncbi.nlm.nih.gov/pubmed/21200698
http://dx.doi.org/10.1107/S1600536807063222
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