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13b,13c-Di-2-pyridyl-5,7,12,13b,13c,14-hexa­hydro-6H,13H-5a,6a,12a,13a-tetra­azabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione methanol hemisolvate

The title compound, C(30)H(24)N(6)O(2)·0.5CH(3)OH, a glycoluril derivative with two pyridine substituents on the convex face of the glycoluril system, is an important inter­mediate for the synthesis of more complex glycoluril derivatives. The compound crystallizes with two independent mol­ecules in...

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Detalles Bibliográficos
Autores principales: Li, Lin, Wang, Zhi-Guo, Wang, Yu-Zhou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915209/
https://www.ncbi.nlm.nih.gov/pubmed/21200705
http://dx.doi.org/10.1107/S1600536807063295
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author Li, Lin
Wang, Zhi-Guo
Wang, Yu-Zhou
author_facet Li, Lin
Wang, Zhi-Guo
Wang, Yu-Zhou
author_sort Li, Lin
collection PubMed
description The title compound, C(30)H(24)N(6)O(2)·0.5CH(3)OH, a glycoluril derivative with two pyridine substituents on the convex face of the glycoluril system, is an important inter­mediate for the synthesis of more complex glycoluril derivatives. The compound crystallizes with two independent mol­ecules in the asymmetric unit, one of which exhibits disorder of one benzene ring over two orientations with refined site occupancy factors 0.65 (4):0.35 (4). The crystal structure contains several short C—H⋯O contacts, and the methanol mol­ecule forms an O—H⋯O hydrogen bond to one of the glycoluril mol­ecules.
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spelling pubmed-29152092010-12-30 13b,13c-Di-2-pyridyl-5,7,12,13b,13c,14-hexa­hydro-6H,13H-5a,6a,12a,13a-tetra­azabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione methanol hemisolvate Li, Lin Wang, Zhi-Guo Wang, Yu-Zhou Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(30)H(24)N(6)O(2)·0.5CH(3)OH, a glycoluril derivative with two pyridine substituents on the convex face of the glycoluril system, is an important inter­mediate for the synthesis of more complex glycoluril derivatives. The compound crystallizes with two independent mol­ecules in the asymmetric unit, one of which exhibits disorder of one benzene ring over two orientations with refined site occupancy factors 0.65 (4):0.35 (4). The crystal structure contains several short C—H⋯O contacts, and the methanol mol­ecule forms an O—H⋯O hydrogen bond to one of the glycoluril mol­ecules. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915209/ /pubmed/21200705 http://dx.doi.org/10.1107/S1600536807063295 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Li, Lin
Wang, Zhi-Guo
Wang, Yu-Zhou
13b,13c-Di-2-pyridyl-5,7,12,13b,13c,14-hexa­hydro-6H,13H-5a,6a,12a,13a-tetra­azabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione methanol hemisolvate
title 13b,13c-Di-2-pyridyl-5,7,12,13b,13c,14-hexa­hydro-6H,13H-5a,6a,12a,13a-tetra­azabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione methanol hemisolvate
title_full 13b,13c-Di-2-pyridyl-5,7,12,13b,13c,14-hexa­hydro-6H,13H-5a,6a,12a,13a-tetra­azabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione methanol hemisolvate
title_fullStr 13b,13c-Di-2-pyridyl-5,7,12,13b,13c,14-hexa­hydro-6H,13H-5a,6a,12a,13a-tetra­azabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione methanol hemisolvate
title_full_unstemmed 13b,13c-Di-2-pyridyl-5,7,12,13b,13c,14-hexa­hydro-6H,13H-5a,6a,12a,13a-tetra­azabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione methanol hemisolvate
title_short 13b,13c-Di-2-pyridyl-5,7,12,13b,13c,14-hexa­hydro-6H,13H-5a,6a,12a,13a-tetra­azabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione methanol hemisolvate
title_sort 13b,13c-di-2-pyridyl-5,7,12,13b,13c,14-hexa­hydro-6h,13h-5a,6a,12a,13a-tetra­azabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione methanol hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915209/
https://www.ncbi.nlm.nih.gov/pubmed/21200705
http://dx.doi.org/10.1107/S1600536807063295
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