2-(4-Bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran

The title compound, C(17)H(15)BrOS, was prepared by the Lewis acid-catalysed reaction of 2,4-dimethyl­phenol with 4′-bromo-2-chloro-2-(methyl­sulfan­yl)acetophenone. The 4-bromo­phenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 8.4 (1)°. The crystal structure is...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915216/
https://www.ncbi.nlm.nih.gov/pubmed/21200712
http://dx.doi.org/10.1107/S1600536807063052
Descripción
Sumario:The title compound, C(17)H(15)BrOS, was prepared by the Lewis acid-catalysed reaction of 2,4-dimethyl­phenol with 4′-bromo-2-chloro-2-(methyl­sulfan­yl)acetophenone. The 4-bromo­phenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 8.4 (1)°. The crystal structure is stabilized by a CH(2)—H⋯π inter­action between the 5-methyl group and the benzene ring of the benzofuran system.

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