2-(4-Bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran

The title compound, C(17)H(15)BrOS, was prepared by the Lewis acid-catalysed reaction of 2,4-dimethyl­phenol with 4′-bromo-2-chloro-2-(methyl­sulfan­yl)acetophenone. The 4-bromo­phenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 8.4 (1)°. The crystal structure is...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915216/
https://www.ncbi.nlm.nih.gov/pubmed/21200712
http://dx.doi.org/10.1107/S1600536807063052
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author Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description The title compound, C(17)H(15)BrOS, was prepared by the Lewis acid-catalysed reaction of 2,4-dimethyl­phenol with 4′-bromo-2-chloro-2-(methyl­sulfan­yl)acetophenone. The 4-bromo­phenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 8.4 (1)°. The crystal structure is stabilized by a CH(2)—H⋯π inter­action between the 5-methyl group and the benzene ring of the benzofuran system.
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spelling pubmed-29152162010-12-30 2-(4-Bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(15)BrOS, was prepared by the Lewis acid-catalysed reaction of 2,4-dimethyl­phenol with 4′-bromo-2-chloro-2-(methyl­sulfan­yl)acetophenone. The 4-bromo­phenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 8.4 (1)°. The crystal structure is stabilized by a CH(2)—H⋯π inter­action between the 5-methyl group and the benzene ring of the benzofuran system. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915216/ /pubmed/21200712 http://dx.doi.org/10.1107/S1600536807063052 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
2-(4-Bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran
title 2-(4-Bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran
title_full 2-(4-Bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran
title_fullStr 2-(4-Bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran
title_full_unstemmed 2-(4-Bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran
title_short 2-(4-Bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran
title_sort 2-(4-bromo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915216/
https://www.ncbi.nlm.nih.gov/pubmed/21200712
http://dx.doi.org/10.1107/S1600536807063052
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AT seopilja 24bromophenyl57dimethyl3methylsulfanyl1benzofuran
AT sonbyengwha 24bromophenyl57dimethyl3methylsulfanyl1benzofuran
AT leeuk 24bromophenyl57dimethyl3methylsulfanyl1benzofuran

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