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6-Chloro-N′-(2-hydroxy-1-naphthylmethylene)nicotinohydrazide
The title compound, C(17)H(12)ClN(3)O(2), was synthesized by the Schiff base condensation reaction of 2-hydroxy-1-naphthaldehyde with 6-chloronicotinic acid hydrazide in a methanol solution. The molecule displays a trans configuration with respect to the C=N and C—N bonds. The dihedral angle betw...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915218/ https://www.ncbi.nlm.nih.gov/pubmed/21200715 http://dx.doi.org/10.1107/S1600536807063611 |
Sumario: | The title compound, C(17)H(12)ClN(3)O(2), was synthesized by the Schiff base condensation reaction of 2-hydroxy-1-naphthaldehyde with 6-chloronicotinic acid hydrazide in a methanol solution. The molecule displays a trans configuration with respect to the C=N and C—N bonds. The dihedral angle between the naphthyl ring system and the pyridine ring is 7.6 (4)°. There is an intramolecular O—H⋯N hydrogen bond. The crystal structure is stabilized by intermolecular N—H⋯O and C—H⋯O hydrogen bonds, forming chains running along the b axis. |
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