10,11-Dihydro­diindeno[1,2-b:2′,1′-d]thio­phene

The title compound, C(18)H(12)S, comprises five fused rings forming an essentially planar mol­ecule, with a total puckering amplitude (Q) of 0.032 Å and a maximum deviation from the mean plane of 0.014 (4) Å for the C atoms of the methyl­ene groups. A crystallographic mirror plane orthogonal to the...

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Detalles Bibliográficos
Autores principales: Afonina, Irina, Coles, Simon J., Hursthouse, Michael B., Kanibolotsky, Alexander, Skabara, Peter J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915234/
https://www.ncbi.nlm.nih.gov/pubmed/21200732
http://dx.doi.org/10.1107/S1600536807063684
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author Afonina, Irina
Coles, Simon J.
Hursthouse, Michael B.
Kanibolotsky, Alexander
Skabara, Peter J.
author_facet Afonina, Irina
Coles, Simon J.
Hursthouse, Michael B.
Kanibolotsky, Alexander
Skabara, Peter J.
author_sort Afonina, Irina
collection PubMed
description The title compound, C(18)H(12)S, comprises five fused rings forming an essentially planar mol­ecule, with a total puckering amplitude (Q) of 0.032 Å and a maximum deviation from the mean plane of 0.014 (4) Å for the C atoms of the methyl­ene groups. A crystallographic mirror plane orthogonal to the mol­ecular plane passes through the S atom and the midpoint of the opposite C—C bond within the central five-membered ring. The mol­ecules lie in layers, forming edge-to-face C—H⋯π inter­actions, with a separation of 2.66 Å between one H atom of the methyl­ene group and the centroid of an adjacent indene ring.
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spelling pubmed-29152342010-12-30 10,11-Dihydro­diindeno[1,2-b:2′,1′-d]thio­phene Afonina, Irina Coles, Simon J. Hursthouse, Michael B. Kanibolotsky, Alexander Skabara, Peter J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(12)S, comprises five fused rings forming an essentially planar mol­ecule, with a total puckering amplitude (Q) of 0.032 Å and a maximum deviation from the mean plane of 0.014 (4) Å for the C atoms of the methyl­ene groups. A crystallographic mirror plane orthogonal to the mol­ecular plane passes through the S atom and the midpoint of the opposite C—C bond within the central five-membered ring. The mol­ecules lie in layers, forming edge-to-face C—H⋯π inter­actions, with a separation of 2.66 Å between one H atom of the methyl­ene group and the centroid of an adjacent indene ring. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915234/ /pubmed/21200732 http://dx.doi.org/10.1107/S1600536807063684 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Afonina, Irina
Coles, Simon J.
Hursthouse, Michael B.
Kanibolotsky, Alexander
Skabara, Peter J.
10,11-Dihydro­diindeno[1,2-b:2′,1′-d]thio­phene
title 10,11-Dihydro­diindeno[1,2-b:2′,1′-d]thio­phene
title_full 10,11-Dihydro­diindeno[1,2-b:2′,1′-d]thio­phene
title_fullStr 10,11-Dihydro­diindeno[1,2-b:2′,1′-d]thio­phene
title_full_unstemmed 10,11-Dihydro­diindeno[1,2-b:2′,1′-d]thio­phene
title_short 10,11-Dihydro­diindeno[1,2-b:2′,1′-d]thio­phene
title_sort 10,11-dihydro­diindeno[1,2-b:2′,1′-d]thio­phene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915234/
https://www.ncbi.nlm.nih.gov/pubmed/21200732
http://dx.doi.org/10.1107/S1600536807063684
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AT kanibolotskyalexander 1011dihydrodiindeno12b21dthiophene
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