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N (2),N (2′)-Bis(2,2-dimethylpropanoyl)benzene-1,3-dicarbohydrazide
In the molecular structure of the title hydrazide derivative, C(18)H(26)N(4)O(4), the conformations of the two units of 2-(2,2-dimethyl-1-oxopropyl)hydrazide substituents are not planar; these two units are attached axially to the benzene ring with C(ortho)—C—C(=O)—N torsion angles of 28.1 (2) and...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915239/ https://www.ncbi.nlm.nih.gov/pubmed/21200739 http://dx.doi.org/10.1107/S1600536807063210 |
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author | Fun, Hoong-Kun Chantrapromma, Suchada Jana, Subrata Hazra, Anita Goswami, Shyamaprosad |
author_facet | Fun, Hoong-Kun Chantrapromma, Suchada Jana, Subrata Hazra, Anita Goswami, Shyamaprosad |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the molecular structure of the title hydrazide derivative, C(18)H(26)N(4)O(4), the conformations of the two units of 2-(2,2-dimethyl-1-oxopropyl)hydrazide substituents are not planar; these two units are attached axially to the benzene ring with C(ortho)—C—C(=O)—N torsion angles of 28.1 (2) and 31.0 (2)° [where C(ortho) is the C atom at position 4 of the benzene ring relative to the substituent at position 3 or the C atom at position 6 of the benzene ring relative to the substituent at position 1, as appropriate]. The dihedral angles between the hydrazide units and the benzene ring are 62.66 (7) and 63.84 (7)°. In the crystal structure, molecules are arranged in an anti-parallel manner and are linked by N—H⋯O intermolecular hydrogen bonds and weak C—H⋯O intermolecular interactions into a three-dimensional network. The structure is further stabilized by a weak C—H⋯N intramolecular interaction. |
format | Text |
id | pubmed-2915239 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29152392010-12-30 N (2),N (2′)-Bis(2,2-dimethylpropanoyl)benzene-1,3-dicarbohydrazide Fun, Hoong-Kun Chantrapromma, Suchada Jana, Subrata Hazra, Anita Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecular structure of the title hydrazide derivative, C(18)H(26)N(4)O(4), the conformations of the two units of 2-(2,2-dimethyl-1-oxopropyl)hydrazide substituents are not planar; these two units are attached axially to the benzene ring with C(ortho)—C—C(=O)—N torsion angles of 28.1 (2) and 31.0 (2)° [where C(ortho) is the C atom at position 4 of the benzene ring relative to the substituent at position 3 or the C atom at position 6 of the benzene ring relative to the substituent at position 1, as appropriate]. The dihedral angles between the hydrazide units and the benzene ring are 62.66 (7) and 63.84 (7)°. In the crystal structure, molecules are arranged in an anti-parallel manner and are linked by N—H⋯O intermolecular hydrogen bonds and weak C—H⋯O intermolecular interactions into a three-dimensional network. The structure is further stabilized by a weak C—H⋯N intramolecular interaction. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915239/ /pubmed/21200739 http://dx.doi.org/10.1107/S1600536807063210 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Organic Papers Fun, Hoong-Kun Chantrapromma, Suchada Jana, Subrata Hazra, Anita Goswami, Shyamaprosad N (2),N (2′)-Bis(2,2-dimethylpropanoyl)benzene-1,3-dicarbohydrazide |
title |
N
(2),N
(2′)-Bis(2,2-dimethylpropanoyl)benzene-1,3-dicarbohydrazide |
title_full |
N
(2),N
(2′)-Bis(2,2-dimethylpropanoyl)benzene-1,3-dicarbohydrazide |
title_fullStr |
N
(2),N
(2′)-Bis(2,2-dimethylpropanoyl)benzene-1,3-dicarbohydrazide |
title_full_unstemmed |
N
(2),N
(2′)-Bis(2,2-dimethylpropanoyl)benzene-1,3-dicarbohydrazide |
title_short |
N
(2),N
(2′)-Bis(2,2-dimethylpropanoyl)benzene-1,3-dicarbohydrazide |
title_sort | n
(2),n
(2′)-bis(2,2-dimethylpropanoyl)benzene-1,3-dicarbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915239/ https://www.ncbi.nlm.nih.gov/pubmed/21200739 http://dx.doi.org/10.1107/S1600536807063210 |
work_keys_str_mv | AT funhoongkun n2n2bis22dimethylpropanoylbenzene13dicarbohydrazide AT chantraprommasuchada n2n2bis22dimethylpropanoylbenzene13dicarbohydrazide AT janasubrata n2n2bis22dimethylpropanoylbenzene13dicarbohydrazide AT hazraanita n2n2bis22dimethylpropanoylbenzene13dicarbohydrazide AT goswamishyamaprosad n2n2bis22dimethylpropanoylbenzene13dicarbohydrazide |