2-Benzoyl­pyridine semicarbazone

The title compound, C(13)H(12)N(4)O, crystallizes with two independent mol­ecules in the asymmetric unit. The compound crystallizes as the ZE isomer, where Z and E refer to the configuration around the C=N and N—C bonds, respectively, with an N—H⋯N(py) (py is pyridine) intra­molecular hydrogen bond....

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Detalles Bibliográficos
Autores principales: de Lima, Daniel F., Pérez-Rebolledo, Anayive, Ellena, Javier, Beraldo, Heloisa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915240/
https://www.ncbi.nlm.nih.gov/pubmed/21200740
http://dx.doi.org/10.1107/S1600536807064628
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author de Lima, Daniel F.
Pérez-Rebolledo, Anayive
Ellena, Javier
Beraldo, Heloisa
author_facet de Lima, Daniel F.
Pérez-Rebolledo, Anayive
Ellena, Javier
Beraldo, Heloisa
author_sort de Lima, Daniel F.
collection PubMed
description The title compound, C(13)H(12)N(4)O, crystallizes with two independent mol­ecules in the asymmetric unit. The compound crystallizes as the ZE isomer, where Z and E refer to the configuration around the C=N and N—C bonds, respectively, with an N—H⋯N(py) (py is pyridine) intra­molecular hydrogen bond. The dihedral angles between the least-squares planes through the semicarbazone group and the pyridyl ring are 22.70 (9) and 27.26 (9)° for the two mol­ecules. There are intermolecular N—H⋯O hydrogen bonds.
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spelling pubmed-29152402010-12-30 2-Benzoyl­pyridine semicarbazone de Lima, Daniel F. Pérez-Rebolledo, Anayive Ellena, Javier Beraldo, Heloisa Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(12)N(4)O, crystallizes with two independent mol­ecules in the asymmetric unit. The compound crystallizes as the ZE isomer, where Z and E refer to the configuration around the C=N and N—C bonds, respectively, with an N—H⋯N(py) (py is pyridine) intra­molecular hydrogen bond. The dihedral angles between the least-squares planes through the semicarbazone group and the pyridyl ring are 22.70 (9) and 27.26 (9)° for the two mol­ecules. There are intermolecular N—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915240/ /pubmed/21200740 http://dx.doi.org/10.1107/S1600536807064628 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
de Lima, Daniel F.
Pérez-Rebolledo, Anayive
Ellena, Javier
Beraldo, Heloisa
2-Benzoyl­pyridine semicarbazone
title 2-Benzoyl­pyridine semicarbazone
title_full 2-Benzoyl­pyridine semicarbazone
title_fullStr 2-Benzoyl­pyridine semicarbazone
title_full_unstemmed 2-Benzoyl­pyridine semicarbazone
title_short 2-Benzoyl­pyridine semicarbazone
title_sort 2-benzoyl­pyridine semicarbazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915240/
https://www.ncbi.nlm.nih.gov/pubmed/21200740
http://dx.doi.org/10.1107/S1600536807064628
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AT beraldoheloisa 2benzoylpyridinesemicarbazone

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