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Bis[(E)-4-(hydroxyiminomethyl)pyridinium] oxalate
The formula unit of the title compound, 2C(6)H(7)N(2)O(+)·C(2)O(4) (2−), comprises two symmetry-equivalent 4-(hydroxyiminomethyl)pyridinium cations on general positions, linked through hydrogen bonding via an oxalate anion that resides on a crystallographic centre of symmetry. The crystal struct...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915244/ https://www.ncbi.nlm.nih.gov/pubmed/21200745 http://dx.doi.org/10.1107/S1600536807064136 |
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author | Seidel, Rüdiger W. Winter, Manuela V. Oppel, Iris M. |
author_facet | Seidel, Rüdiger W. Winter, Manuela V. Oppel, Iris M. |
author_sort | Seidel, Rüdiger W. |
collection | PubMed |
description | The formula unit of the title compound, 2C(6)H(7)N(2)O(+)·C(2)O(4) (2−), comprises two symmetry-equivalent 4-(hydroxyiminomethyl)pyridinium cations on general positions, linked through hydrogen bonding via an oxalate anion that resides on a crystallographic centre of symmetry. The crystal structure consists of infinite chains of cations and oxalate anions directed by O—H⋯O and multicentre N—H⋯O intermolecular hydrogen-bonding interactions. |
format | Text |
id | pubmed-2915244 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29152442010-12-30 Bis[(E)-4-(hydroxyiminomethyl)pyridinium] oxalate Seidel, Rüdiger W. Winter, Manuela V. Oppel, Iris M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The formula unit of the title compound, 2C(6)H(7)N(2)O(+)·C(2)O(4) (2−), comprises two symmetry-equivalent 4-(hydroxyiminomethyl)pyridinium cations on general positions, linked through hydrogen bonding via an oxalate anion that resides on a crystallographic centre of symmetry. The crystal structure consists of infinite chains of cations and oxalate anions directed by O—H⋯O and multicentre N—H⋯O intermolecular hydrogen-bonding interactions. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915244/ /pubmed/21200745 http://dx.doi.org/10.1107/S1600536807064136 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Organic Papers Seidel, Rüdiger W. Winter, Manuela V. Oppel, Iris M. Bis[(E)-4-(hydroxyiminomethyl)pyridinium] oxalate |
title | Bis[(E)-4-(hydroxyiminomethyl)pyridinium] oxalate |
title_full | Bis[(E)-4-(hydroxyiminomethyl)pyridinium] oxalate |
title_fullStr | Bis[(E)-4-(hydroxyiminomethyl)pyridinium] oxalate |
title_full_unstemmed | Bis[(E)-4-(hydroxyiminomethyl)pyridinium] oxalate |
title_short | Bis[(E)-4-(hydroxyiminomethyl)pyridinium] oxalate |
title_sort | bis[(e)-4-(hydroxyiminomethyl)pyridinium] oxalate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915244/ https://www.ncbi.nlm.nih.gov/pubmed/21200745 http://dx.doi.org/10.1107/S1600536807064136 |
work_keys_str_mv | AT seidelrudigerw bise4hydroxyiminomethylpyridiniumoxalate AT wintermanuelav bise4hydroxyiminomethylpyridiniumoxalate AT oppelirism bise4hydroxyiminomethylpyridiniumoxalate |