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9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate)
The cation of the title compound, C(36)H(34)N(6)O(2) (2+)·2PF(6) (−), lies across a crystallographic inversion centre. The imidazole and pyridine rings form dihedral angles of 82.28 (5)° and 11.87 (7)°, respectively, with the anthracene ring system. The crystal packing is stabilized by π–π interact...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915252/ https://www.ncbi.nlm.nih.gov/pubmed/21200753 http://dx.doi.org/10.1107/S1600536807063842 |
| _version_ | 1782184896597327872 |
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| author | Guo, Li-Hui Qin, Da-Bin Gu, Shao-Jin Wang, Gui-Yu Luo, Jie-Wei |
| author_facet | Guo, Li-Hui Qin, Da-Bin Gu, Shao-Jin Wang, Gui-Yu Luo, Jie-Wei |
| author_sort | Guo, Li-Hui |
| collection | PubMed |
| description | The cation of the title compound, C(36)H(34)N(6)O(2) (2+)·2PF(6) (−), lies across a crystallographic inversion centre. The imidazole and pyridine rings form dihedral angles of 82.28 (5)° and 11.87 (7)°, respectively, with the anthracene ring system. The crystal packing is stabilized by π–π interactions between the pyridine ring and the central ring of anthracene, with a ring centroid–centroid distance of 3.684 (3) Å. The PF(6) (−) anion is disordered over three different positions with occupancies of 0.284 (6), 0.354 (8) and 0.362 (9). |
| format | Text |
| id | pubmed-2915252 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29152522010-12-30 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) Guo, Li-Hui Qin, Da-Bin Gu, Shao-Jin Wang, Gui-Yu Luo, Jie-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The cation of the title compound, C(36)H(34)N(6)O(2) (2+)·2PF(6) (−), lies across a crystallographic inversion centre. The imidazole and pyridine rings form dihedral angles of 82.28 (5)° and 11.87 (7)°, respectively, with the anthracene ring system. The crystal packing is stabilized by π–π interactions between the pyridine ring and the central ring of anthracene, with a ring centroid–centroid distance of 3.684 (3) Å. The PF(6) (−) anion is disordered over three different positions with occupancies of 0.284 (6), 0.354 (8) and 0.362 (9). International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915252/ /pubmed/21200753 http://dx.doi.org/10.1107/S1600536807063842 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Organic Papers Guo, Li-Hui Qin, Da-Bin Gu, Shao-Jin Wang, Gui-Yu Luo, Jie-Wei 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_full | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_fullStr | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_full_unstemmed | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_short | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_sort | 9,10-bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915252/ https://www.ncbi.nlm.nih.gov/pubmed/21200753 http://dx.doi.org/10.1107/S1600536807063842 |
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