5,10,15,20-Tetra­kis(3,5-difluoro­phen­yl)porphyrin

The crystal structure of the title compound, C(44)H(22)F(8)N(4), shows an unusual non-planar geometry of the porphyrin ring although the mol­ecule is free of steric crowding around the periphery of the macrocycle. The mol­ecular packing exhibits weak inter­molecular hydrogen bonding (C—H⋯F) and C—H⋯...

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Detalles Bibliográficos
Autores principales: Bhyrappa, P., Velkannan, V., Varghese, B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915253/
https://www.ncbi.nlm.nih.gov/pubmed/21200755
http://dx.doi.org/10.1107/S1600536807062782
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author Bhyrappa, P.
Velkannan, V.
Varghese, B.
author_facet Bhyrappa, P.
Velkannan, V.
Varghese, B.
author_sort Bhyrappa, P.
collection PubMed
description The crystal structure of the title compound, C(44)H(22)F(8)N(4), shows an unusual non-planar geometry of the porphyrin ring although the mol­ecule is free of steric crowding around the periphery of the macrocycle. The mol­ecular packing exhibits weak inter­molecular hydrogen bonding (C—H⋯F) and C—H⋯π inter­actions. The molecular symmetry is [Image: see text].
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spelling pubmed-29152532010-12-30 5,10,15,20-Tetra­kis(3,5-difluoro­phen­yl)porphyrin Bhyrappa, P. Velkannan, V. Varghese, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(44)H(22)F(8)N(4), shows an unusual non-planar geometry of the porphyrin ring although the mol­ecule is free of steric crowding around the periphery of the macrocycle. The mol­ecular packing exhibits weak inter­molecular hydrogen bonding (C—H⋯F) and C—H⋯π inter­actions. The molecular symmetry is [Image: see text]. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915253/ /pubmed/21200755 http://dx.doi.org/10.1107/S1600536807062782 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Bhyrappa, P.
Velkannan, V.
Varghese, B.
5,10,15,20-Tetra­kis(3,5-difluoro­phen­yl)porphyrin
title 5,10,15,20-Tetra­kis(3,5-difluoro­phen­yl)porphyrin
title_full 5,10,15,20-Tetra­kis(3,5-difluoro­phen­yl)porphyrin
title_fullStr 5,10,15,20-Tetra­kis(3,5-difluoro­phen­yl)porphyrin
title_full_unstemmed 5,10,15,20-Tetra­kis(3,5-difluoro­phen­yl)porphyrin
title_short 5,10,15,20-Tetra­kis(3,5-difluoro­phen­yl)porphyrin
title_sort 5,10,15,20-tetra­kis(3,5-difluoro­phen­yl)porphyrin
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915253/
https://www.ncbi.nlm.nih.gov/pubmed/21200755
http://dx.doi.org/10.1107/S1600536807062782
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AT velkannanv 5101520tetrakis35difluorophenylporphyrin
AT vargheseb 5101520tetrakis35difluorophenylporphyrin

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