2-Chloro-N-(3-methyl­phen­yl)acetamide

The conformation of the N—H bond in the structure of the title compound, C(9)H(10)ClNO, is syn to the meta-methyl group, in contrast to the anti conformation observed with respect to the meta-nitro group in 2-chloro-N-(3-nitro­phen­yl)­acetamide. The asymmetric unit of the title compound contains tw...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Svoboda, Ingrid, Foro, Sabine, Dou, Shi-qi, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915269/
https://www.ncbi.nlm.nih.gov/pubmed/21200773
http://dx.doi.org/10.1107/S1600536807064847
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author Gowda, B. Thimme
Svoboda, Ingrid
Foro, Sabine
Dou, Shi-qi
Fuess, Hartmut
author_facet Gowda, B. Thimme
Svoboda, Ingrid
Foro, Sabine
Dou, Shi-qi
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The conformation of the N—H bond in the structure of the title compound, C(9)H(10)ClNO, is syn to the meta-methyl group, in contrast to the anti conformation observed with respect to the meta-nitro group in 2-chloro-N-(3-nitro­phen­yl)­acetamide. The asymmetric unit of the title compound contains two mol­ecules. The geometric parameters of the title compound are similar to those of 2-chloro-N-(4-methyl­phen­yl)­acetamide, 2-chloro-N-(3-nitro­phen­yl)acetamide and other acetanilides. Dual inter­molecular N—H⋯O hydrogen bonds link the mol­ecules in the direction of the a axis.
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spelling pubmed-29152692010-12-30 2-Chloro-N-(3-methyl­phen­yl)acetamide Gowda, B. Thimme Svoboda, Ingrid Foro, Sabine Dou, Shi-qi Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The conformation of the N—H bond in the structure of the title compound, C(9)H(10)ClNO, is syn to the meta-methyl group, in contrast to the anti conformation observed with respect to the meta-nitro group in 2-chloro-N-(3-nitro­phen­yl)­acetamide. The asymmetric unit of the title compound contains two mol­ecules. The geometric parameters of the title compound are similar to those of 2-chloro-N-(4-methyl­phen­yl)­acetamide, 2-chloro-N-(3-nitro­phen­yl)acetamide and other acetanilides. Dual inter­molecular N—H⋯O hydrogen bonds link the mol­ecules in the direction of the a axis. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915269/ /pubmed/21200773 http://dx.doi.org/10.1107/S1600536807064847 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Gowda, B. Thimme
Svoboda, Ingrid
Foro, Sabine
Dou, Shi-qi
Fuess, Hartmut
2-Chloro-N-(3-methyl­phen­yl)acetamide
title 2-Chloro-N-(3-methyl­phen­yl)acetamide
title_full 2-Chloro-N-(3-methyl­phen­yl)acetamide
title_fullStr 2-Chloro-N-(3-methyl­phen­yl)acetamide
title_full_unstemmed 2-Chloro-N-(3-methyl­phen­yl)acetamide
title_short 2-Chloro-N-(3-methyl­phen­yl)acetamide
title_sort 2-chloro-n-(3-methyl­phen­yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915269/
https://www.ncbi.nlm.nih.gov/pubmed/21200773
http://dx.doi.org/10.1107/S1600536807064847
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AT svobodaingrid 2chloron3methylphenylacetamide
AT forosabine 2chloron3methylphenylacetamide
AT doushiqi 2chloron3methylphenylacetamide
AT fuesshartmut 2chloron3methylphenylacetamide

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