2-(2,3,5,6-Tetra­fluoro-4-iodo­anilino)­ethanol

The reaction of 2-amino­ethanol and iodo­penta­fluoro­benzene in the presence of K(2)CO(3) gave the title compound, C(8)H(6)F(4)INO, in high yield. The structure is characterized by double layers of mol­ecules linked by O—H⋯O and N—H⋯O hydrogen bonds, and linear C—I⋯F [I⋯F = 3.049 (2) Å] and bent C—...

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Detalles Bibliográficos
Autores principales: Metrangolo, Pierangelo, Meyer, Franck, Pilati, Tullio, Resnati, Giuseppe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915272/
https://www.ncbi.nlm.nih.gov/pubmed/21200777
http://dx.doi.org/10.1107/S1600536807064197
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author Metrangolo, Pierangelo
Meyer, Franck
Pilati, Tullio
Resnati, Giuseppe
author_facet Metrangolo, Pierangelo
Meyer, Franck
Pilati, Tullio
Resnati, Giuseppe
author_sort Metrangolo, Pierangelo
collection PubMed
description The reaction of 2-amino­ethanol and iodo­penta­fluoro­benzene in the presence of K(2)CO(3) gave the title compound, C(8)H(6)F(4)INO, in high yield. The structure is characterized by double layers of mol­ecules linked by O—H⋯O and N—H⋯O hydrogen bonds, and linear C—I⋯F [I⋯F = 3.049 (2) Å] and bent C—I⋯I [I⋯I = 3.9388 (7) Å] inter­actions between pairs of nearly parallel iodo­tetra­fluoro­phenyl groups. No O⋯I or N⋯I halogen bonding is found.
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spelling pubmed-29152722010-12-30 2-(2,3,5,6-Tetra­fluoro-4-iodo­anilino)­ethanol Metrangolo, Pierangelo Meyer, Franck Pilati, Tullio Resnati, Giuseppe Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of 2-amino­ethanol and iodo­penta­fluoro­benzene in the presence of K(2)CO(3) gave the title compound, C(8)H(6)F(4)INO, in high yield. The structure is characterized by double layers of mol­ecules linked by O—H⋯O and N—H⋯O hydrogen bonds, and linear C—I⋯F [I⋯F = 3.049 (2) Å] and bent C—I⋯I [I⋯I = 3.9388 (7) Å] inter­actions between pairs of nearly parallel iodo­tetra­fluoro­phenyl groups. No O⋯I or N⋯I halogen bonding is found. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915272/ /pubmed/21200777 http://dx.doi.org/10.1107/S1600536807064197 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Metrangolo, Pierangelo
Meyer, Franck
Pilati, Tullio
Resnati, Giuseppe
2-(2,3,5,6-Tetra­fluoro-4-iodo­anilino)­ethanol
title 2-(2,3,5,6-Tetra­fluoro-4-iodo­anilino)­ethanol
title_full 2-(2,3,5,6-Tetra­fluoro-4-iodo­anilino)­ethanol
title_fullStr 2-(2,3,5,6-Tetra­fluoro-4-iodo­anilino)­ethanol
title_full_unstemmed 2-(2,3,5,6-Tetra­fluoro-4-iodo­anilino)­ethanol
title_short 2-(2,3,5,6-Tetra­fluoro-4-iodo­anilino)­ethanol
title_sort 2-(2,3,5,6-tetra­fluoro-4-iodo­anilino)­ethanol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915272/
https://www.ncbi.nlm.nih.gov/pubmed/21200777
http://dx.doi.org/10.1107/S1600536807064197
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AT pilatitullio 22356tetrafluoro4iodoanilinoethanol
AT resnatigiuseppe 22356tetrafluoro4iodoanilinoethanol

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