(Z)-N-[2-(Dimethyl­ammonio)eth­yl]thio­acetamide chloride

The thio­amide and quaternary amine parts of the title compound, C(6)H(15)N(2)S(+)·Cl(−), are mutually almost perpendicular, the dihedral angle being 80.6 (7)°. The thio­amide group is planar and adopts a Z conformation, whereas the amine end of the cation is in an extended conformation. In the supr...

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Detalles Bibliográficos
Autores principales: Dutkiewicz, Grzegorz, Borowiak, Teresa, Spychała, Jarosław
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915290/
https://www.ncbi.nlm.nih.gov/pubmed/21200796
http://dx.doi.org/10.1107/S1600536807064872
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author Dutkiewicz, Grzegorz
Borowiak, Teresa
Spychała, Jarosław
author_facet Dutkiewicz, Grzegorz
Borowiak, Teresa
Spychała, Jarosław
author_sort Dutkiewicz, Grzegorz
collection PubMed
description The thio­amide and quaternary amine parts of the title compound, C(6)H(15)N(2)S(+)·Cl(−), are mutually almost perpendicular, the dihedral angle being 80.6 (7)°. The thio­amide group is planar and adopts a Z conformation, whereas the amine end of the cation is in an extended conformation. In the supra­molecular structure, mol­ecules are linked into centrosymmetric dimers by two hydrogen bonds: N—H(amine)⋯Cl and N—H(thio­amide)⋯Cl.
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spelling pubmed-29152902010-12-30 (Z)-N-[2-(Dimethyl­ammonio)eth­yl]thio­acetamide chloride Dutkiewicz, Grzegorz Borowiak, Teresa Spychała, Jarosław Acta Crystallogr Sect E Struct Rep Online Organic Papers The thio­amide and quaternary amine parts of the title compound, C(6)H(15)N(2)S(+)·Cl(−), are mutually almost perpendicular, the dihedral angle being 80.6 (7)°. The thio­amide group is planar and adopts a Z conformation, whereas the amine end of the cation is in an extended conformation. In the supra­molecular structure, mol­ecules are linked into centrosymmetric dimers by two hydrogen bonds: N—H(amine)⋯Cl and N—H(thio­amide)⋯Cl. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915290/ /pubmed/21200796 http://dx.doi.org/10.1107/S1600536807064872 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Dutkiewicz, Grzegorz
Borowiak, Teresa
Spychała, Jarosław
(Z)-N-[2-(Dimethyl­ammonio)eth­yl]thio­acetamide chloride
title (Z)-N-[2-(Dimethyl­ammonio)eth­yl]thio­acetamide chloride
title_full (Z)-N-[2-(Dimethyl­ammonio)eth­yl]thio­acetamide chloride
title_fullStr (Z)-N-[2-(Dimethyl­ammonio)eth­yl]thio­acetamide chloride
title_full_unstemmed (Z)-N-[2-(Dimethyl­ammonio)eth­yl]thio­acetamide chloride
title_short (Z)-N-[2-(Dimethyl­ammonio)eth­yl]thio­acetamide chloride
title_sort (z)-n-[2-(dimethyl­ammonio)eth­yl]thio­acetamide chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915290/
https://www.ncbi.nlm.nih.gov/pubmed/21200796
http://dx.doi.org/10.1107/S1600536807064872
work_keys_str_mv AT dutkiewiczgrzegorz zn2dimethylammonioethylthioacetamidechloride
AT borowiakteresa zn2dimethylammonioethylthioacetamidechloride
AT spychałajarosław zn2dimethylammonioethylthioacetamidechloride

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