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2,2-Dichloro-N-(2,3-dimethylphenyl)acetamide
The conformation of the N—H bond in the title compound, C(10)H(11)Cl(2)NO, is syn to both the 2- and 3-methyl substituents in the aromatic ring, similar to that of the 2-chloro and 3-chloro substituents in 2,2-dichloro-N-(2,3-dichlorophenyl)acetamide and the 2-methyl substituent in 2,2-dichloro-N-...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915294/ https://www.ncbi.nlm.nih.gov/pubmed/21200801 http://dx.doi.org/10.1107/S1600536807064550 |
Sumario: | The conformation of the N—H bond in the title compound, C(10)H(11)Cl(2)NO, is syn to both the 2- and 3-methyl substituents in the aromatic ring, similar to that of the 2-chloro and 3-chloro substituents in 2,2-dichloro-N-(2,3-dichlorophenyl)acetamide and the 2-methyl substituent in 2,2-dichloro-N-(2-methylphenyl)acetamide, but in contrast to the anti conformation observed with respect to the 3-methyl substituent in 2,2-dichloro-N-(3-methylphenyl)acetamide. The bond parameters in the title compound are similar to those in 2,2-dichloro-N-phenylacetamide and other acetanilides. The molecules of the title compound are linked into chains through N—H⋯O and C—H⋯O hydrogen bonding. |
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