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2,4,6-Tris(4-fluorophenyl)-2-(1-pyridyl)-boroxine
Crystals of the title compound, C(23)H(17)B(3)F(3)NO(3), were obtained unintentionally by slow evaporation of a chloroform solution of the preformed boroxine–pyridine adduct. The molecule contains three fluoro-substituted benzene rings, each bonded to one of the three B atoms of a six-membered bor...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915295/ https://www.ncbi.nlm.nih.gov/pubmed/21200802 http://dx.doi.org/10.1107/S1600536807064367 |
Sumario: | Crystals of the title compound, C(23)H(17)B(3)F(3)NO(3), were obtained unintentionally by slow evaporation of a chloroform solution of the preformed boroxine–pyridine adduct. The molecule contains three fluoro-substituted benzene rings, each bonded to one of the three B atoms of a six-membered boroxine ring. A pyridyl ring is also bound to one of the B atoms through a Lewis acid–base interaction. The binding of the pyridyl substituent causes the otherwise planar boroxine ring to twist, resulting in a maximum torsion angle within the ring of 17.6 (2)°. |
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