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2,4,6-Tris­(4-fluoro­phen­yl)-2-(1-pyrid­yl)-boroxine

Crystals of the title compound, C(23)H(17)B(3)F(3)NO(3), were obtained unintentionally by slow evaporation of a chloro­form solution of the preformed boroxine–pyridine adduct. The mol­ecule contains three fluoro-substituted benzene rings, each bonded to one of the three B atoms of a six-membered bor...

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Detalles Bibliográficos
Autores principales: Pearson, Wayne H., Lin, Shirley, Iovine, Peter M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915295/
https://www.ncbi.nlm.nih.gov/pubmed/21200802
http://dx.doi.org/10.1107/S1600536807064367
Descripción
Sumario:Crystals of the title compound, C(23)H(17)B(3)F(3)NO(3), were obtained unintentionally by slow evaporation of a chloro­form solution of the preformed boroxine–pyridine adduct. The mol­ecule contains three fluoro-substituted benzene rings, each bonded to one of the three B atoms of a six-membered boroxine ring. A pyridyl ring is also bound to one of the B atoms through a Lewis acid–base inter­action. The binding of the pyridyl substituent causes the otherwise planar boroxine ring to twist, resulting in a maximum torsion angle within the ring of 17.6 (2)°.