2,3,4,6-Tetra-O-benzoyl-4-nitro­phenyl-1-thio-α-d-mannopyran­oside–dichloro­methane–diethyl ether mixed solvate (1/0.53/0.38)

The title compound, C(40)H(31)NO(11)S·0.53CH(2)Cl(2)·0.38C(4)H(10)O, was synthesized in two steps from mannose penta­acetate and single crystals were grown by slow evaporation. The structure was determined by single-crystal X-ray diffraction, confirming the α-configuration of the anomeric thioaryl s...

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Detalles Bibliográficos
Autores principales: Drouin, Ludovic, Cowley, Andrew R., Fairbanks, Antony J., Thompson, Amber L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915296/
https://www.ncbi.nlm.nih.gov/pubmed/21200803
http://dx.doi.org/10.1107/S1600536807064951
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author Drouin, Ludovic
Cowley, Andrew R.
Fairbanks, Antony J.
Thompson, Amber L.
author_facet Drouin, Ludovic
Cowley, Andrew R.
Fairbanks, Antony J.
Thompson, Amber L.
author_sort Drouin, Ludovic
collection PubMed
description The title compound, C(40)H(31)NO(11)S·0.53CH(2)Cl(2)·0.38C(4)H(10)O, was synthesized in two steps from mannose penta­acetate and single crystals were grown by slow evaporation. The structure was determined by single-crystal X-ray diffraction, confirming the α-configuration of the anomeric thioaryl substituent. The asymmetric unit contains two crystallographically distinct mol­ecules of the carbohydrate. The central pyran­ose rings of these are geometrically similar, but there are differences in the orientations of the benzoate substituents.
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spelling pubmed-29152962010-12-30 2,3,4,6-Tetra-O-benzoyl-4-nitro­phenyl-1-thio-α-d-mannopyran­oside–dichloro­methane–diethyl ether mixed solvate (1/0.53/0.38) Drouin, Ludovic Cowley, Andrew R. Fairbanks, Antony J. Thompson, Amber L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(40)H(31)NO(11)S·0.53CH(2)Cl(2)·0.38C(4)H(10)O, was synthesized in two steps from mannose penta­acetate and single crystals were grown by slow evaporation. The structure was determined by single-crystal X-ray diffraction, confirming the α-configuration of the anomeric thioaryl substituent. The asymmetric unit contains two crystallographically distinct mol­ecules of the carbohydrate. The central pyran­ose rings of these are geometrically similar, but there are differences in the orientations of the benzoate substituents. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915296/ /pubmed/21200803 http://dx.doi.org/10.1107/S1600536807064951 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Drouin, Ludovic
Cowley, Andrew R.
Fairbanks, Antony J.
Thompson, Amber L.
2,3,4,6-Tetra-O-benzoyl-4-nitro­phenyl-1-thio-α-d-mannopyran­oside–dichloro­methane–diethyl ether mixed solvate (1/0.53/0.38)
title 2,3,4,6-Tetra-O-benzoyl-4-nitro­phenyl-1-thio-α-d-mannopyran­oside–dichloro­methane–diethyl ether mixed solvate (1/0.53/0.38)
title_full 2,3,4,6-Tetra-O-benzoyl-4-nitro­phenyl-1-thio-α-d-mannopyran­oside–dichloro­methane–diethyl ether mixed solvate (1/0.53/0.38)
title_fullStr 2,3,4,6-Tetra-O-benzoyl-4-nitro­phenyl-1-thio-α-d-mannopyran­oside–dichloro­methane–diethyl ether mixed solvate (1/0.53/0.38)
title_full_unstemmed 2,3,4,6-Tetra-O-benzoyl-4-nitro­phenyl-1-thio-α-d-mannopyran­oside–dichloro­methane–diethyl ether mixed solvate (1/0.53/0.38)
title_short 2,3,4,6-Tetra-O-benzoyl-4-nitro­phenyl-1-thio-α-d-mannopyran­oside–dichloro­methane–diethyl ether mixed solvate (1/0.53/0.38)
title_sort 2,3,4,6-tetra-o-benzoyl-4-nitro­phenyl-1-thio-α-d-mannopyran­oside–dichloro­methane–diethyl ether mixed solvate (1/0.53/0.38)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915296/
https://www.ncbi.nlm.nih.gov/pubmed/21200803
http://dx.doi.org/10.1107/S1600536807064951
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AT fairbanksantonyj 2346tetraobenzoyl4nitrophenyl1thioadmannopyranosidedichloromethanediethylethermixedsolvate1053038
AT thompsonamberl 2346tetraobenzoyl4nitrophenyl1thioadmannopyranosidedichloromethanediethylethermixedsolvate1053038

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