1-Hydr­oxy-1,1,3,3,3-penta­phenyl­disiloxane, [Si(2)O(OH)(Ph)(5)], at 100 K

In the crystal structure of the title compound, C(30)H(26)O(2)Si(2), one Si(Ph)(3) residue is bound to another Si(OH)(Ph)(2) residue via a non-linear Si—O—Si bridge. The asymmetric unit is composed of two such molecules which inter­act, on the one hand, via a strong and highly directional O—H⋯O hydr...

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Detalles Bibliográficos
Autores principales: Coelho, Ana C., Amarante, Tatiana R., Klinowski, Jacek, Gonçalves, Isabel S., Almeida Paz, Filipe A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915297/
https://www.ncbi.nlm.nih.gov/pubmed/21200804
http://dx.doi.org/10.1107/S1600536807064975
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author Coelho, Ana C.
Amarante, Tatiana R.
Klinowski, Jacek
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_facet Coelho, Ana C.
Amarante, Tatiana R.
Klinowski, Jacek
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_sort Coelho, Ana C.
collection PubMed
description In the crystal structure of the title compound, C(30)H(26)O(2)Si(2), one Si(Ph)(3) residue is bound to another Si(OH)(Ph)(2) residue via a non-linear Si—O—Si bridge. The asymmetric unit is composed of two such molecules which inter­act, on the one hand, via a strong and highly directional O—H⋯O hydrogen bond involving the two neighbouring Si—OH units and, on the other, via an O—H⋯π contact connecting the second hydroxyl group with an adjacent phenyl group.
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spelling pubmed-29152972010-12-30 1-Hydr­oxy-1,1,3,3,3-penta­phenyl­disiloxane, [Si(2)O(OH)(Ph)(5)], at 100 K Coelho, Ana C. Amarante, Tatiana R. Klinowski, Jacek Gonçalves, Isabel S. Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(30)H(26)O(2)Si(2), one Si(Ph)(3) residue is bound to another Si(OH)(Ph)(2) residue via a non-linear Si—O—Si bridge. The asymmetric unit is composed of two such molecules which inter­act, on the one hand, via a strong and highly directional O—H⋯O hydrogen bond involving the two neighbouring Si—OH units and, on the other, via an O—H⋯π contact connecting the second hydroxyl group with an adjacent phenyl group. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915297/ /pubmed/21200804 http://dx.doi.org/10.1107/S1600536807064975 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Coelho, Ana C.
Amarante, Tatiana R.
Klinowski, Jacek
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
1-Hydr­oxy-1,1,3,3,3-penta­phenyl­disiloxane, [Si(2)O(OH)(Ph)(5)], at 100 K
title 1-Hydr­oxy-1,1,3,3,3-penta­phenyl­disiloxane, [Si(2)O(OH)(Ph)(5)], at 100 K
title_full 1-Hydr­oxy-1,1,3,3,3-penta­phenyl­disiloxane, [Si(2)O(OH)(Ph)(5)], at 100 K
title_fullStr 1-Hydr­oxy-1,1,3,3,3-penta­phenyl­disiloxane, [Si(2)O(OH)(Ph)(5)], at 100 K
title_full_unstemmed 1-Hydr­oxy-1,1,3,3,3-penta­phenyl­disiloxane, [Si(2)O(OH)(Ph)(5)], at 100 K
title_short 1-Hydr­oxy-1,1,3,3,3-penta­phenyl­disiloxane, [Si(2)O(OH)(Ph)(5)], at 100 K
title_sort 1-hydr­oxy-1,1,3,3,3-penta­phenyl­disiloxane, [si(2)o(oh)(ph)(5)], at 100 k
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915297/
https://www.ncbi.nlm.nih.gov/pubmed/21200804
http://dx.doi.org/10.1107/S1600536807064975
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