N-[(S)-1-(3,5-Dimethyl-2-hydroxy­phenyl)­ethyl]-N-[(R)-2-hydr­oxy-1-phenyl­ethyl]ammonium chloride

In the title compound, C(18)H(24)NO(2) (+)·Cl(−), the absolute configuration of the new stereogenic centre (the C atom with a CH(2)OH substituent) was unambiguously determined to have an R configuration. The dihedral angle between the two aromatic rings is 30.82 (2)°. Inter­molecular N—H⋯Cl and O—H⋯...

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Detalles Bibliográficos
Autores principales: Zhang, Guangyou, Gu, Xungang, Wang, Xiangbo, Wang, Wanhui, Li, Shuchun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915299/
https://www.ncbi.nlm.nih.gov/pubmed/21200807
http://dx.doi.org/10.1107/S1600536807063106
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author Zhang, Guangyou
Gu, Xungang
Wang, Xiangbo
Wang, Wanhui
Li, Shuchun
author_facet Zhang, Guangyou
Gu, Xungang
Wang, Xiangbo
Wang, Wanhui
Li, Shuchun
author_sort Zhang, Guangyou
collection PubMed
description In the title compound, C(18)H(24)NO(2) (+)·Cl(−), the absolute configuration of the new stereogenic centre (the C atom with a CH(2)OH substituent) was unambiguously determined to have an R configuration. The dihedral angle between the two aromatic rings is 30.82 (2)°. Inter­molecular N—H⋯Cl and O—H⋯Cl hydrogen bonds and intra­molecular N—H⋯O hydrogen bonds stabilize the crystal structure.
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spelling pubmed-29152992010-12-30 N-[(S)-1-(3,5-Dimethyl-2-hydroxy­phenyl)­ethyl]-N-[(R)-2-hydr­oxy-1-phenyl­ethyl]ammonium chloride Zhang, Guangyou Gu, Xungang Wang, Xiangbo Wang, Wanhui Li, Shuchun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(24)NO(2) (+)·Cl(−), the absolute configuration of the new stereogenic centre (the C atom with a CH(2)OH substituent) was unambiguously determined to have an R configuration. The dihedral angle between the two aromatic rings is 30.82 (2)°. Inter­molecular N—H⋯Cl and O—H⋯Cl hydrogen bonds and intra­molecular N—H⋯O hydrogen bonds stabilize the crystal structure. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915299/ /pubmed/21200807 http://dx.doi.org/10.1107/S1600536807063106 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Zhang, Guangyou
Gu, Xungang
Wang, Xiangbo
Wang, Wanhui
Li, Shuchun
N-[(S)-1-(3,5-Dimethyl-2-hydroxy­phenyl)­ethyl]-N-[(R)-2-hydr­oxy-1-phenyl­ethyl]ammonium chloride
title N-[(S)-1-(3,5-Dimethyl-2-hydroxy­phenyl)­ethyl]-N-[(R)-2-hydr­oxy-1-phenyl­ethyl]ammonium chloride
title_full N-[(S)-1-(3,5-Dimethyl-2-hydroxy­phenyl)­ethyl]-N-[(R)-2-hydr­oxy-1-phenyl­ethyl]ammonium chloride
title_fullStr N-[(S)-1-(3,5-Dimethyl-2-hydroxy­phenyl)­ethyl]-N-[(R)-2-hydr­oxy-1-phenyl­ethyl]ammonium chloride
title_full_unstemmed N-[(S)-1-(3,5-Dimethyl-2-hydroxy­phenyl)­ethyl]-N-[(R)-2-hydr­oxy-1-phenyl­ethyl]ammonium chloride
title_short N-[(S)-1-(3,5-Dimethyl-2-hydroxy­phenyl)­ethyl]-N-[(R)-2-hydr­oxy-1-phenyl­ethyl]ammonium chloride
title_sort n-[(s)-1-(3,5-dimethyl-2-hydroxy­phenyl)­ethyl]-n-[(r)-2-hydr­oxy-1-phenyl­ethyl]ammonium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915299/
https://www.ncbi.nlm.nih.gov/pubmed/21200807
http://dx.doi.org/10.1107/S1600536807063106
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AT wangxiangbo ns135dimethyl2hydroxyphenylethylnr2hydroxy1phenylethylammoniumchloride
AT wangwanhui ns135dimethyl2hydroxyphenylethylnr2hydroxy1phenylethylammoniumchloride
AT lishuchun ns135dimethyl2hydroxyphenylethylnr2hydroxy1phenylethylammoniumchloride

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