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N-Phenyl-N-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline

The title compound, C(25)H(18)N(4)O, is a non-planar bipolar ligand containing triphenyl­amine and 1,3,4-oxadiazole units. In the mol­ecule, the benzene ring, the 1,3,4-oxadiazole ring, and the pyridine ring are twisted slightly with respect to each other [dihedral angle between the benzene and 1,3,...

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Detalles Bibliográficos
Autores principales: Han, Li-Ping, Li, Bin, Liu, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915300/
https://www.ncbi.nlm.nih.gov/pubmed/21200808
http://dx.doi.org/10.1107/S1600536807065245
Descripción
Sumario:The title compound, C(25)H(18)N(4)O, is a non-planar bipolar ligand containing triphenyl­amine and 1,3,4-oxadiazole units. In the mol­ecule, the benzene ring, the 1,3,4-oxadiazole ring, and the pyridine ring are twisted slightly with respect to each other [dihedral angle between the benzene and 1,3,4-oxadiazole rings = 9.4 (4) and between the 1,3,4-oxadiazole and pyridine rings = 3.0 (4)°]. Moreover, the dihedral angles between the two phenyl rings and the benzene ring are 88.2 (4) and 113.3 (4)°, and that between the two phenyl rings is 67.9 (4)°. The closest distances between the pyridine ring and the 1,3,4-oxadiazole and benzene rings in adjacent mol­ecules are 3.316 and 3.363 Å, respectively, indicating the existence of π–π inter­actions.