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N-Phenyl-N-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline

The title compound, C(25)H(18)N(4)O, is a non-planar bipolar ligand containing triphenyl­amine and 1,3,4-oxadiazole units. In the mol­ecule, the benzene ring, the 1,3,4-oxadiazole ring, and the pyridine ring are twisted slightly with respect to each other [dihedral angle between the benzene and 1,3,...

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Detalles Bibliográficos
Autores principales: Han, Li-Ping, Li, Bin, Liu, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915300/
https://www.ncbi.nlm.nih.gov/pubmed/21200808
http://dx.doi.org/10.1107/S1600536807065245
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author Han, Li-Ping
Li, Bin
Liu, Jie
author_facet Han, Li-Ping
Li, Bin
Liu, Jie
author_sort Han, Li-Ping
collection PubMed
description The title compound, C(25)H(18)N(4)O, is a non-planar bipolar ligand containing triphenyl­amine and 1,3,4-oxadiazole units. In the mol­ecule, the benzene ring, the 1,3,4-oxadiazole ring, and the pyridine ring are twisted slightly with respect to each other [dihedral angle between the benzene and 1,3,4-oxadiazole rings = 9.4 (4) and between the 1,3,4-oxadiazole and pyridine rings = 3.0 (4)°]. Moreover, the dihedral angles between the two phenyl rings and the benzene ring are 88.2 (4) and 113.3 (4)°, and that between the two phenyl rings is 67.9 (4)°. The closest distances between the pyridine ring and the 1,3,4-oxadiazole and benzene rings in adjacent mol­ecules are 3.316 and 3.363 Å, respectively, indicating the existence of π–π inter­actions.
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spelling pubmed-29153002010-12-30 N-Phenyl-N-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline Han, Li-Ping Li, Bin Liu, Jie Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(18)N(4)O, is a non-planar bipolar ligand containing triphenyl­amine and 1,3,4-oxadiazole units. In the mol­ecule, the benzene ring, the 1,3,4-oxadiazole ring, and the pyridine ring are twisted slightly with respect to each other [dihedral angle between the benzene and 1,3,4-oxadiazole rings = 9.4 (4) and between the 1,3,4-oxadiazole and pyridine rings = 3.0 (4)°]. Moreover, the dihedral angles between the two phenyl rings and the benzene ring are 88.2 (4) and 113.3 (4)°, and that between the two phenyl rings is 67.9 (4)°. The closest distances between the pyridine ring and the 1,3,4-oxadiazole and benzene rings in adjacent mol­ecules are 3.316 and 3.363 Å, respectively, indicating the existence of π–π inter­actions. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915300/ /pubmed/21200808 http://dx.doi.org/10.1107/S1600536807065245 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Han, Li-Ping
Li, Bin
Liu, Jie
N-Phenyl-N-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline
title N-Phenyl-N-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline
title_full N-Phenyl-N-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline
title_fullStr N-Phenyl-N-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline
title_full_unstemmed N-Phenyl-N-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline
title_short N-Phenyl-N-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline
title_sort n-phenyl-n-{4-[5-(4-pyrid­yl)-1,3,4-oxadiazol-2-yl]phen­yl}aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915300/
https://www.ncbi.nlm.nih.gov/pubmed/21200808
http://dx.doi.org/10.1107/S1600536807065245
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