1,3-Bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate

The cation of the title salt, C(34)H(45)N(2) (+)·PF(6) (−), is a protonated form of an unsymmetrical overcrowded β-imino­amine. The observed bond lengths [C—N = 1.326 (4)–1.341 (4) Å and C—C = 1.383 (4)–1.391 (4) Å] suggest significant delocalization within the π system of the N C C C N backbone....

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Detalles Bibliográficos
Autores principales: Elmkacher, Najoua Belhaj Mbarek, Rzaigui, Mohamed, Bouachir, Faouzi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915305/
https://www.ncbi.nlm.nih.gov/pubmed/21200813
http://dx.doi.org/10.1107/S1600536807065543
Descripción
Sumario:The cation of the title salt, C(34)H(45)N(2) (+)·PF(6) (−), is a protonated form of an unsymmetrical overcrowded β-imino­amine. The observed bond lengths [C—N = 1.326 (4)–1.341 (4) Å and C—C = 1.383 (4)–1.391 (4) Å] suggest significant delocalization within the π system of the N C C C N backbone.

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