1,3-Bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate

The cation of the title salt, C(34)H(45)N(2) (+)·PF(6) (−), is a protonated form of an unsymmetrical overcrowded β-imino­amine. The observed bond lengths [C—N = 1.326 (4)–1.341 (4) Å and C—C = 1.383 (4)–1.391 (4) Å] suggest significant delocalization within the π system of the N C C C N backbone....

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Detalles Bibliográficos
Autores principales: Elmkacher, Najoua Belhaj Mbarek, Rzaigui, Mohamed, Bouachir, Faouzi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915305/
https://www.ncbi.nlm.nih.gov/pubmed/21200813
http://dx.doi.org/10.1107/S1600536807065543
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author Elmkacher, Najoua Belhaj Mbarek
Rzaigui, Mohamed
Bouachir, Faouzi
author_facet Elmkacher, Najoua Belhaj Mbarek
Rzaigui, Mohamed
Bouachir, Faouzi
author_sort Elmkacher, Najoua Belhaj Mbarek
collection PubMed
description The cation of the title salt, C(34)H(45)N(2) (+)·PF(6) (−), is a protonated form of an unsymmetrical overcrowded β-imino­amine. The observed bond lengths [C—N = 1.326 (4)–1.341 (4) Å and C—C = 1.383 (4)–1.391 (4) Å] suggest significant delocalization within the π system of the N C C C N backbone.
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spelling pubmed-29153052010-12-30 1,3-Bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate Elmkacher, Najoua Belhaj Mbarek Rzaigui, Mohamed Bouachir, Faouzi Acta Crystallogr Sect E Struct Rep Online Organic Papers The cation of the title salt, C(34)H(45)N(2) (+)·PF(6) (−), is a protonated form of an unsymmetrical overcrowded β-imino­amine. The observed bond lengths [C—N = 1.326 (4)–1.341 (4) Å and C—C = 1.383 (4)–1.391 (4) Å] suggest significant delocalization within the π system of the N C C C N backbone. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915305/ /pubmed/21200813 http://dx.doi.org/10.1107/S1600536807065543 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Elmkacher, Najoua Belhaj Mbarek
Rzaigui, Mohamed
Bouachir, Faouzi
1,3-Bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate
title 1,3-Bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate
title_full 1,3-Bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate
title_fullStr 1,3-Bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate
title_full_unstemmed 1,3-Bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate
title_short 1,3-Bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate
title_sort 1,3-bis(2,6-diisopropyl­anilino)-1-phenyl­butyl­ium hexa­fluorido­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915305/
https://www.ncbi.nlm.nih.gov/pubmed/21200813
http://dx.doi.org/10.1107/S1600536807065543
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AT rzaiguimohamed 13bis26diisopropylanilino1phenylbutyliumhexafluoridophosphate
AT bouachirfaouzi 13bis26diisopropylanilino1phenylbutyliumhexafluoridophosphate

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