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Dibenzyl penta­thio­dicarbonate

In the title compound, C(16)H(14)S(5), the non-bonded intra­molecular distances between the non-terminal S atoms are 2.808 (16) and 2.784 (16) Å, shorter than the typical distance of 2.9 Å. One phenyl ring participates in an offset π-π inter­action with another phenyl ring related by a centre of inv...

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Detalles Bibliográficos
Autores principales: Weber, Wolfgang G., McLeary, James B., Gertenbach, Jan-André, Loots, Leigh
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915307/
https://www.ncbi.nlm.nih.gov/pubmed/21200815
http://dx.doi.org/10.1107/S1600536807065488
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author Weber, Wolfgang G.
McLeary, James B.
Gertenbach, Jan-André
Loots, Leigh
author_facet Weber, Wolfgang G.
McLeary, James B.
Gertenbach, Jan-André
Loots, Leigh
author_sort Weber, Wolfgang G.
collection PubMed
description In the title compound, C(16)H(14)S(5), the non-bonded intra­molecular distances between the non-terminal S atoms are 2.808 (16) and 2.784 (16) Å, shorter than the typical distance of 2.9 Å. One phenyl ring participates in an offset π-π inter­action with another phenyl ring related by a centre of inversion; the inter­planar distance is 3.41 (2) Å. The crystal structure also exhibits edge-to-face C—H⋯π stacking of the phenyl rings, thus forming a herring-bone packing motif.
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spelling pubmed-29153072010-12-30 Dibenzyl penta­thio­dicarbonate Weber, Wolfgang G. McLeary, James B. Gertenbach, Jan-André Loots, Leigh Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(14)S(5), the non-bonded intra­molecular distances between the non-terminal S atoms are 2.808 (16) and 2.784 (16) Å, shorter than the typical distance of 2.9 Å. One phenyl ring participates in an offset π-π inter­action with another phenyl ring related by a centre of inversion; the inter­planar distance is 3.41 (2) Å. The crystal structure also exhibits edge-to-face C—H⋯π stacking of the phenyl rings, thus forming a herring-bone packing motif. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915307/ /pubmed/21200815 http://dx.doi.org/10.1107/S1600536807065488 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Weber, Wolfgang G.
McLeary, James B.
Gertenbach, Jan-André
Loots, Leigh
Dibenzyl penta­thio­dicarbonate
title Dibenzyl penta­thio­dicarbonate
title_full Dibenzyl penta­thio­dicarbonate
title_fullStr Dibenzyl penta­thio­dicarbonate
title_full_unstemmed Dibenzyl penta­thio­dicarbonate
title_short Dibenzyl penta­thio­dicarbonate
title_sort dibenzyl penta­thio­dicarbonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915307/
https://www.ncbi.nlm.nih.gov/pubmed/21200815
http://dx.doi.org/10.1107/S1600536807065488
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