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Dibenzyl pentathiodicarbonate
In the title compound, C(16)H(14)S(5), the non-bonded intramolecular distances between the non-terminal S atoms are 2.808 (16) and 2.784 (16) Å, shorter than the typical distance of 2.9 Å. One phenyl ring participates in an offset π-π interaction with another phenyl ring related by a centre of inv...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915307/ https://www.ncbi.nlm.nih.gov/pubmed/21200815 http://dx.doi.org/10.1107/S1600536807065488 |
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author | Weber, Wolfgang G. McLeary, James B. Gertenbach, Jan-André Loots, Leigh |
author_facet | Weber, Wolfgang G. McLeary, James B. Gertenbach, Jan-André Loots, Leigh |
author_sort | Weber, Wolfgang G. |
collection | PubMed |
description | In the title compound, C(16)H(14)S(5), the non-bonded intramolecular distances between the non-terminal S atoms are 2.808 (16) and 2.784 (16) Å, shorter than the typical distance of 2.9 Å. One phenyl ring participates in an offset π-π interaction with another phenyl ring related by a centre of inversion; the interplanar distance is 3.41 (2) Å. The crystal structure also exhibits edge-to-face C—H⋯π stacking of the phenyl rings, thus forming a herring-bone packing motif. |
format | Text |
id | pubmed-2915307 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29153072010-12-30 Dibenzyl pentathiodicarbonate Weber, Wolfgang G. McLeary, James B. Gertenbach, Jan-André Loots, Leigh Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(14)S(5), the non-bonded intramolecular distances between the non-terminal S atoms are 2.808 (16) and 2.784 (16) Å, shorter than the typical distance of 2.9 Å. One phenyl ring participates in an offset π-π interaction with another phenyl ring related by a centre of inversion; the interplanar distance is 3.41 (2) Å. The crystal structure also exhibits edge-to-face C—H⋯π stacking of the phenyl rings, thus forming a herring-bone packing motif. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915307/ /pubmed/21200815 http://dx.doi.org/10.1107/S1600536807065488 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Organic Papers Weber, Wolfgang G. McLeary, James B. Gertenbach, Jan-André Loots, Leigh Dibenzyl pentathiodicarbonate |
title | Dibenzyl pentathiodicarbonate |
title_full | Dibenzyl pentathiodicarbonate |
title_fullStr | Dibenzyl pentathiodicarbonate |
title_full_unstemmed | Dibenzyl pentathiodicarbonate |
title_short | Dibenzyl pentathiodicarbonate |
title_sort | dibenzyl pentathiodicarbonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915307/ https://www.ncbi.nlm.nih.gov/pubmed/21200815 http://dx.doi.org/10.1107/S1600536807065488 |
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