N-(2-Chloro­quinolin-3-ylmethyl­ene)aniline

The title compound, C(16)H(11)ClN(2), displays a trans configuration across the C=N bond and a transoid arrangement across the quinoline ring and the azomethine C atom. This arrangement facilitates C—H⋯Cl interactions. The packing in the crystal structure is due to inter­molecular C—H⋯π and Cl⋯π (3....

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Autores principales: Kalkhambkar, Rajesh G., Kulkarni, Geeta M., Hwang, Wen-Shu, Lee, Chen-Shiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915315/
https://www.ncbi.nlm.nih.gov/pubmed/21200823
http://dx.doi.org/10.1107/S1600536807064690
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author Kalkhambkar, Rajesh G.
Kulkarni, Geeta M.
Hwang, Wen-Shu
Lee, Chen-Shiang
author_facet Kalkhambkar, Rajesh G.
Kulkarni, Geeta M.
Hwang, Wen-Shu
Lee, Chen-Shiang
author_sort Kalkhambkar, Rajesh G.
collection PubMed
description The title compound, C(16)H(11)ClN(2), displays a trans configuration across the C=N bond and a transoid arrangement across the quinoline ring and the azomethine C atom. This arrangement facilitates C—H⋯Cl interactions. The packing in the crystal structure is due to inter­molecular C—H⋯π and Cl⋯π (3.52 and 3.84 Å) inter­actions. The dihedral angle between the least-squares planes of 2-chloro­quinoline and phenyl­amine is 16.61 (2)°.
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spelling pubmed-29153152010-12-30 N-(2-Chloro­quinolin-3-ylmethyl­ene)aniline Kalkhambkar, Rajesh G. Kulkarni, Geeta M. Hwang, Wen-Shu Lee, Chen-Shiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(11)ClN(2), displays a trans configuration across the C=N bond and a transoid arrangement across the quinoline ring and the azomethine C atom. This arrangement facilitates C—H⋯Cl interactions. The packing in the crystal structure is due to inter­molecular C—H⋯π and Cl⋯π (3.52 and 3.84 Å) inter­actions. The dihedral angle between the least-squares planes of 2-chloro­quinoline and phenyl­amine is 16.61 (2)°. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915315/ /pubmed/21200823 http://dx.doi.org/10.1107/S1600536807064690 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Kalkhambkar, Rajesh G.
Kulkarni, Geeta M.
Hwang, Wen-Shu
Lee, Chen-Shiang
N-(2-Chloro­quinolin-3-ylmethyl­ene)aniline
title N-(2-Chloro­quinolin-3-ylmethyl­ene)aniline
title_full N-(2-Chloro­quinolin-3-ylmethyl­ene)aniline
title_fullStr N-(2-Chloro­quinolin-3-ylmethyl­ene)aniline
title_full_unstemmed N-(2-Chloro­quinolin-3-ylmethyl­ene)aniline
title_short N-(2-Chloro­quinolin-3-ylmethyl­ene)aniline
title_sort n-(2-chloro­quinolin-3-ylmethyl­ene)aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915315/
https://www.ncbi.nlm.nih.gov/pubmed/21200823
http://dx.doi.org/10.1107/S1600536807064690
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