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4-Hydroxy-4,6a,6b,9,9,12a,14b-heptamethylperhydropicen-3-one hemihydrate isolated from Adiantum incisum
The title compound, C(29)H(48)O(2)·0.5H(2)O, is a triterpenoid isolated from the stems and rhizomes of Adiantum incisum. The basic skeleton of the molecule contains five six-membered rings, all adopting chair conformations, bearing a total of seven methyl, one hydroxyl and a keto group. There are t...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915320/ https://www.ncbi.nlm.nih.gov/pubmed/21200829 http://dx.doi.org/10.1107/S1600536807064021 |
Sumario: | The title compound, C(29)H(48)O(2)·0.5H(2)O, is a triterpenoid isolated from the stems and rhizomes of Adiantum incisum. The basic skeleton of the molecule contains five six-membered rings, all adopting chair conformations, bearing a total of seven methyl, one hydroxyl and a keto group. There are two molecules of the triterpene and one water molecule of crystallization in the asymmetric unit. The two unique triterpenoid molecules hydrogen-bond directly via an O—H⋯O=C interaction, and are also bridged by the water molecule. The water also bridges to another pair of hydrogen-bonded triterpenoid molecules. |
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