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Dipropyl 4,8-dioxo-1H,5H-2,6-dioxa-3a,4a,7a,8a-tetra­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate

The title compound, C(16)H(22)N(4)O(8), is a glycoluril derivative with two propoxycarbonyl substituents on the convex face of the glycoluril system. The dihedral angle between the five-membered rings in the glycoluril unit is 72.70 (2)°. The oxadiazinane six-membered ring displays a normal chair co...

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Detalles Bibliográficos
Autores principales: Wang, Shuai, Hu, Yan, Gao, Meng, Wang, Zi-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915321/
https://www.ncbi.nlm.nih.gov/pubmed/21200830
http://dx.doi.org/10.1107/S1600536807065853
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author Wang, Shuai
Hu, Yan
Gao, Meng
Wang, Zi-Hua
author_facet Wang, Shuai
Hu, Yan
Gao, Meng
Wang, Zi-Hua
author_sort Wang, Shuai
collection PubMed
description The title compound, C(16)H(22)N(4)O(8), is a glycoluril derivative with two propoxycarbonyl substituents on the convex face of the glycoluril system. The dihedral angle between the five-membered rings in the glycoluril unit is 72.70 (2)°. The oxadiazinane six-membered ring displays a normal chair conformation. One of the propyl groups is disordered over two positions with site occupancies of 0.557 (7) and 0.443 (7). Inter­molecular C—H⋯O hydrogen bonds are effective in the stabilization of the crystal structure.
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spelling pubmed-29153212010-12-30 Dipropyl 4,8-dioxo-1H,5H-2,6-dioxa-3a,4a,7a,8a-tetra­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate Wang, Shuai Hu, Yan Gao, Meng Wang, Zi-Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(22)N(4)O(8), is a glycoluril derivative with two propoxycarbonyl substituents on the convex face of the glycoluril system. The dihedral angle between the five-membered rings in the glycoluril unit is 72.70 (2)°. The oxadiazinane six-membered ring displays a normal chair conformation. One of the propyl groups is disordered over two positions with site occupancies of 0.557 (7) and 0.443 (7). Inter­molecular C—H⋯O hydrogen bonds are effective in the stabilization of the crystal structure. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915321/ /pubmed/21200830 http://dx.doi.org/10.1107/S1600536807065853 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Wang, Shuai
Hu, Yan
Gao, Meng
Wang, Zi-Hua
Dipropyl 4,8-dioxo-1H,5H-2,6-dioxa-3a,4a,7a,8a-tetra­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate
title Dipropyl 4,8-dioxo-1H,5H-2,6-dioxa-3a,4a,7a,8a-tetra­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate
title_full Dipropyl 4,8-dioxo-1H,5H-2,6-dioxa-3a,4a,7a,8a-tetra­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate
title_fullStr Dipropyl 4,8-dioxo-1H,5H-2,6-dioxa-3a,4a,7a,8a-tetra­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate
title_full_unstemmed Dipropyl 4,8-dioxo-1H,5H-2,6-dioxa-3a,4a,7a,8a-tetra­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate
title_short Dipropyl 4,8-dioxo-1H,5H-2,6-dioxa-3a,4a,7a,8a-tetra­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate
title_sort dipropyl 4,8-dioxo-1h,5h-2,6-dioxa-3a,4a,7a,8a-tetra­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915321/
https://www.ncbi.nlm.nih.gov/pubmed/21200830
http://dx.doi.org/10.1107/S1600536807065853
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