2-(9H-Fluoren-9-ylidenemeth­yl)thio­phene

The title compound, C(18)H(12)S, contains a thio­phene ring which is disordered by rotation of 180° about the linking C—C bond. The site occupancies of the major and minor components of the disordered ring are 0.900 (3) and 0.100 (3), respectively. In one of these disordered components, the mol­ecul...

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Detalles Bibliográficos
Autores principales: Perašínová, Lucia, Štefko, Martin, Végh, Daniel, Kožíšek, Jozef
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915328/
https://www.ncbi.nlm.nih.gov/pubmed/21200839
http://dx.doi.org/10.1107/S1600536807065099
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author Perašínová, Lucia
Štefko, Martin
Végh, Daniel
Kožíšek, Jozef
author_facet Perašínová, Lucia
Štefko, Martin
Végh, Daniel
Kožíšek, Jozef
author_sort Perašínová, Lucia
collection PubMed
description The title compound, C(18)H(12)S, contains a thio­phene ring which is disordered by rotation of 180° about the linking C—C bond. The site occupancies of the major and minor components of the disordered ring are 0.900 (3) and 0.100 (3), respectively. In one of these disordered components, the mol­ecule is stabilized by an intra­molecular C—H⋯S hydrogen bond. The compound was synthesized in good yield (80%) by a modified phase-transfer-catalysed condensation of fluorene with thio­phene-2-carbaldehyde.
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spelling pubmed-29153282010-12-30 2-(9H-Fluoren-9-ylidenemeth­yl)thio­phene Perašínová, Lucia Štefko, Martin Végh, Daniel Kožíšek, Jozef Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(12)S, contains a thio­phene ring which is disordered by rotation of 180° about the linking C—C bond. The site occupancies of the major and minor components of the disordered ring are 0.900 (3) and 0.100 (3), respectively. In one of these disordered components, the mol­ecule is stabilized by an intra­molecular C—H⋯S hydrogen bond. The compound was synthesized in good yield (80%) by a modified phase-transfer-catalysed condensation of fluorene with thio­phene-2-carbaldehyde. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915328/ /pubmed/21200839 http://dx.doi.org/10.1107/S1600536807065099 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Perašínová, Lucia
Štefko, Martin
Végh, Daniel
Kožíšek, Jozef
2-(9H-Fluoren-9-ylidenemeth­yl)thio­phene
title 2-(9H-Fluoren-9-ylidenemeth­yl)thio­phene
title_full 2-(9H-Fluoren-9-ylidenemeth­yl)thio­phene
title_fullStr 2-(9H-Fluoren-9-ylidenemeth­yl)thio­phene
title_full_unstemmed 2-(9H-Fluoren-9-ylidenemeth­yl)thio­phene
title_short 2-(9H-Fluoren-9-ylidenemeth­yl)thio­phene
title_sort 2-(9h-fluoren-9-ylidenemeth­yl)thio­phene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915328/
https://www.ncbi.nlm.nih.gov/pubmed/21200839
http://dx.doi.org/10.1107/S1600536807065099
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AT stefkomartin 29hfluoren9ylidenemethylthiophene
AT veghdaniel 29hfluoren9ylidenemethylthiophene
AT kozisekjozef 29hfluoren9ylidenemethylthiophene

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