C(60) 1,1,2,2-tetra­chloro­ethyl­ene tetra­solvate

In the title complex, C(60)·4C(2)Cl(4), the C(60) mol­ecule is located on an inversion centre and there are two tetra­chloro­ethyl­ene (TCE) mol­ecules in the asymmetric unit. Both TCE mol­ecules show positional disorder, with occupancy ratios of 0.75:0.25 and 0.56:0.44. Four fullerene C atoms form...

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Detalles Bibliográficos
Autores principales: Arunkumar, C., Bhyrappa, P., Varghese, B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915331/
https://www.ncbi.nlm.nih.gov/pubmed/21200843
http://dx.doi.org/10.1107/S1600536807066329
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author Arunkumar, C.
Bhyrappa, P.
Varghese, B.
author_facet Arunkumar, C.
Bhyrappa, P.
Varghese, B.
author_sort Arunkumar, C.
collection PubMed
description In the title complex, C(60)·4C(2)Cl(4), the C(60) mol­ecule is located on an inversion centre and there are two tetra­chloro­ethyl­ene (TCE) mol­ecules in the asymmetric unit. Both TCE mol­ecules show positional disorder, with occupancy ratios of 0.75:0.25 and 0.56:0.44. Four fullerene C atoms form short contacts [3.208 (17) and 3.223 (17) Å] with the centres of the TCE double bonds, indicating that C(60)–solvent inter­actions are largely π–π in nature.
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spelling pubmed-29153312010-12-30 C(60) 1,1,2,2-tetra­chloro­ethyl­ene tetra­solvate Arunkumar, C. Bhyrappa, P. Varghese, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title complex, C(60)·4C(2)Cl(4), the C(60) mol­ecule is located on an inversion centre and there are two tetra­chloro­ethyl­ene (TCE) mol­ecules in the asymmetric unit. Both TCE mol­ecules show positional disorder, with occupancy ratios of 0.75:0.25 and 0.56:0.44. Four fullerene C atoms form short contacts [3.208 (17) and 3.223 (17) Å] with the centres of the TCE double bonds, indicating that C(60)–solvent inter­actions are largely π–π in nature. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915331/ /pubmed/21200843 http://dx.doi.org/10.1107/S1600536807066329 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Arunkumar, C.
Bhyrappa, P.
Varghese, B.
C(60) 1,1,2,2-tetra­chloro­ethyl­ene tetra­solvate
title C(60) 1,1,2,2-tetra­chloro­ethyl­ene tetra­solvate
title_full C(60) 1,1,2,2-tetra­chloro­ethyl­ene tetra­solvate
title_fullStr C(60) 1,1,2,2-tetra­chloro­ethyl­ene tetra­solvate
title_full_unstemmed C(60) 1,1,2,2-tetra­chloro­ethyl­ene tetra­solvate
title_short C(60) 1,1,2,2-tetra­chloro­ethyl­ene tetra­solvate
title_sort c(60) 1,1,2,2-tetra­chloro­ethyl­ene tetra­solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915331/
https://www.ncbi.nlm.nih.gov/pubmed/21200843
http://dx.doi.org/10.1107/S1600536807066329
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