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trans-Cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate

Although the title mol­ecule, C(20)H(16)N(2)O(10), does not possess mol­ecular inversion symmetry, it lies on a crystallographic inversion centre which imposes disorder on the central cyclo­hexene ring. In addition, the cyclo­hexene ring has non-symmetry-related disorder over two sites, with the rat...

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Detalles Bibliográficos
Autores principales: Nawazish Ali, Syed, Begum, Sabira, Winnik, Mitchell A., Lough, Alan J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915334/
https://www.ncbi.nlm.nih.gov/pubmed/21200847
http://dx.doi.org/10.1107/S1600536807065993
Descripción
Sumario:Although the title mol­ecule, C(20)H(16)N(2)O(10), does not possess mol­ecular inversion symmetry, it lies on a crystallographic inversion centre which imposes disorder on the central cyclo­hexene ring. In addition, the cyclo­hexene ring has non-symmetry-related disorder over two sites, with the ratio of the major and minor components being 0.54:0.46. The overall effect is to produce four disorder components for the atoms of the cyclo­hexene ring. The side chain is perfectly ordered and the dihedral angle between the atoms of the carbonate group (O=CO(2)—) and the benzene ring is 72.99 (6)°.