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trans-Cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate
Although the title molecule, C(20)H(16)N(2)O(10), does not possess molecular inversion symmetry, it lies on a crystallographic inversion centre which imposes disorder on the central cyclohexene ring. In addition, the cyclohexene ring has non-symmetry-related disorder over two sites, with the rat...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915334/ https://www.ncbi.nlm.nih.gov/pubmed/21200847 http://dx.doi.org/10.1107/S1600536807065993 |
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author | Nawazish Ali, Syed Begum, Sabira Winnik, Mitchell A. Lough, Alan J. |
author_facet | Nawazish Ali, Syed Begum, Sabira Winnik, Mitchell A. Lough, Alan J. |
author_sort | Nawazish Ali, Syed |
collection | PubMed |
description | Although the title molecule, C(20)H(16)N(2)O(10), does not possess molecular inversion symmetry, it lies on a crystallographic inversion centre which imposes disorder on the central cyclohexene ring. In addition, the cyclohexene ring has non-symmetry-related disorder over two sites, with the ratio of the major and minor components being 0.54:0.46. The overall effect is to produce four disorder components for the atoms of the cyclohexene ring. The side chain is perfectly ordered and the dihedral angle between the atoms of the carbonate group (O=CO(2)—) and the benzene ring is 72.99 (6)°. |
format | Text |
id | pubmed-2915334 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29153342010-12-30 trans-Cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate Nawazish Ali, Syed Begum, Sabira Winnik, Mitchell A. Lough, Alan J. Acta Crystallogr Sect E Struct Rep Online Organic Papers Although the title molecule, C(20)H(16)N(2)O(10), does not possess molecular inversion symmetry, it lies on a crystallographic inversion centre which imposes disorder on the central cyclohexene ring. In addition, the cyclohexene ring has non-symmetry-related disorder over two sites, with the ratio of the major and minor components being 0.54:0.46. The overall effect is to produce four disorder components for the atoms of the cyclohexene ring. The side chain is perfectly ordered and the dihedral angle between the atoms of the carbonate group (O=CO(2)—) and the benzene ring is 72.99 (6)°. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915334/ /pubmed/21200847 http://dx.doi.org/10.1107/S1600536807065993 Text en © Nawazish Ali et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Nawazish Ali, Syed Begum, Sabira Winnik, Mitchell A. Lough, Alan J. trans-Cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate |
title |
trans-Cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate |
title_full |
trans-Cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate |
title_fullStr |
trans-Cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate |
title_full_unstemmed |
trans-Cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate |
title_short |
trans-Cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate |
title_sort | trans-cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915334/ https://www.ncbi.nlm.nih.gov/pubmed/21200847 http://dx.doi.org/10.1107/S1600536807065993 |
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