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trans-Cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate

Although the title mol­ecule, C(20)H(16)N(2)O(10), does not possess mol­ecular inversion symmetry, it lies on a crystallographic inversion centre which imposes disorder on the central cyclo­hexene ring. In addition, the cyclo­hexene ring has non-symmetry-related disorder over two sites, with the rat...

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Detalles Bibliográficos
Autores principales: Nawazish Ali, Syed, Begum, Sabira, Winnik, Mitchell A., Lough, Alan J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915334/
https://www.ncbi.nlm.nih.gov/pubmed/21200847
http://dx.doi.org/10.1107/S1600536807065993
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author Nawazish Ali, Syed
Begum, Sabira
Winnik, Mitchell A.
Lough, Alan J.
author_facet Nawazish Ali, Syed
Begum, Sabira
Winnik, Mitchell A.
Lough, Alan J.
author_sort Nawazish Ali, Syed
collection PubMed
description Although the title mol­ecule, C(20)H(16)N(2)O(10), does not possess mol­ecular inversion symmetry, it lies on a crystallographic inversion centre which imposes disorder on the central cyclo­hexene ring. In addition, the cyclo­hexene ring has non-symmetry-related disorder over two sites, with the ratio of the major and minor components being 0.54:0.46. The overall effect is to produce four disorder components for the atoms of the cyclo­hexene ring. The side chain is perfectly ordered and the dihedral angle between the atoms of the carbonate group (O=CO(2)—) and the benzene ring is 72.99 (6)°.
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spelling pubmed-29153342010-12-30 trans-Cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate Nawazish Ali, Syed Begum, Sabira Winnik, Mitchell A. Lough, Alan J. Acta Crystallogr Sect E Struct Rep Online Organic Papers Although the title mol­ecule, C(20)H(16)N(2)O(10), does not possess mol­ecular inversion symmetry, it lies on a crystallographic inversion centre which imposes disorder on the central cyclo­hexene ring. In addition, the cyclo­hexene ring has non-symmetry-related disorder over two sites, with the ratio of the major and minor components being 0.54:0.46. The overall effect is to produce four disorder components for the atoms of the cyclo­hexene ring. The side chain is perfectly ordered and the dihedral angle between the atoms of the carbonate group (O=CO(2)—) and the benzene ring is 72.99 (6)°. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915334/ /pubmed/21200847 http://dx.doi.org/10.1107/S1600536807065993 Text en © Nawazish Ali et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nawazish Ali, Syed
Begum, Sabira
Winnik, Mitchell A.
Lough, Alan J.
trans-Cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate
title trans-Cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate
title_full trans-Cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate
title_fullStr trans-Cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate
title_full_unstemmed trans-Cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate
title_short trans-Cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate
title_sort trans-cyclo­hex-2-ene-1,4-diyl bis­(4-nitro­phen­yl) dicarbonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915334/
https://www.ncbi.nlm.nih.gov/pubmed/21200847
http://dx.doi.org/10.1107/S1600536807065993
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