8-(Biphenyl-4-yl)-8-hydroxy­penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethyl­ene ketal

The title compound, C(25)H(24)O(3), synthesized as a potential chiral catalyst, exhibits a range of C—C bond lengths in the penta­cyclo­undecane cage between 1.5144 (18) and 1.5856 (16) Å. The two benzene rings are not planar with respect to each other, but rather are twisted at a torsion angle of 3...

Descripción completa

Detalles Bibliográficos
Autores principales: Boyle, Grant A., Govender, Thavendran, Kruger, Hendrik G., Maguire, Glenn E. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915336/
https://www.ncbi.nlm.nih.gov/pubmed/21200849
http://dx.doi.org/10.1107/S1600536807065920
Descripción
Sumario:The title compound, C(25)H(24)O(3), synthesized as a potential chiral catalyst, exhibits a range of C—C bond lengths in the penta­cyclo­undecane cage between 1.5144 (18) and 1.5856 (16) Å. The two benzene rings are not planar with respect to each other, but rather are twisted at a torsion angle of 34.67 (17)°. The mol­ecule has an intra­molecular O—H⋯O inter­action and participates in two C—H⋯O inter­molecular inter­actions to form a one-dimensional chain.

Ejemplares similares