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8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal
The title compound, C(25)H(24)O(3), synthesized as a potential chiral catalyst, exhibits a range of C—C bond lengths in the pentacycloundecane cage between 1.5144 (18) and 1.5856 (16) Å. The two benzene rings are not planar with respect to each other, but rather are twisted at a torsion angle of 3...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915336/ https://www.ncbi.nlm.nih.gov/pubmed/21200849 http://dx.doi.org/10.1107/S1600536807065920 |
| _version_ | 1782184916603109376 |
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| author | Boyle, Grant A. Govender, Thavendran Kruger, Hendrik G. Maguire, Glenn E. M. |
| author_facet | Boyle, Grant A. Govender, Thavendran Kruger, Hendrik G. Maguire, Glenn E. M. |
| author_sort | Boyle, Grant A. |
| collection | PubMed |
| description | The title compound, C(25)H(24)O(3), synthesized as a potential chiral catalyst, exhibits a range of C—C bond lengths in the pentacycloundecane cage between 1.5144 (18) and 1.5856 (16) Å. The two benzene rings are not planar with respect to each other, but rather are twisted at a torsion angle of 34.67 (17)°. The molecule has an intramolecular O—H⋯O interaction and participates in two C—H⋯O intermolecular interactions to form a one-dimensional chain. |
| format | Text |
| id | pubmed-2915336 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29153362010-12-30 8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal Boyle, Grant A. Govender, Thavendran Kruger, Hendrik G. Maguire, Glenn E. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(24)O(3), synthesized as a potential chiral catalyst, exhibits a range of C—C bond lengths in the pentacycloundecane cage between 1.5144 (18) and 1.5856 (16) Å. The two benzene rings are not planar with respect to each other, but rather are twisted at a torsion angle of 34.67 (17)°. The molecule has an intramolecular O—H⋯O interaction and participates in two C—H⋯O intermolecular interactions to form a one-dimensional chain. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915336/ /pubmed/21200849 http://dx.doi.org/10.1107/S1600536807065920 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Organic Papers Boyle, Grant A. Govender, Thavendran Kruger, Hendrik G. Maguire, Glenn E. M. 8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal |
| title | 8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal |
| title_full | 8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal |
| title_fullStr | 8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal |
| title_full_unstemmed | 8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal |
| title_short | 8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal |
| title_sort | 8-(biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915336/ https://www.ncbi.nlm.nih.gov/pubmed/21200849 http://dx.doi.org/10.1107/S1600536807065920 |
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