Nicotinohydrazide

In the title compound (alternative name: pyridine-3-carbo­hydrazide, C(6)H(7)N(3)O), the asymmetric unit contains a single mol­ecule. In contrast with nicotinic acid and nicotinamide, the C=O bond is found to be oriented cis with respect to the C(ipso) C N fragment in the pyridine ring. The pyridine...

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Detalles Bibliográficos
Autores principales: Portalone, Gustavo, Colapietro, Marcello
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915352/
https://www.ncbi.nlm.nih.gov/pubmed/21200868
http://dx.doi.org/10.1107/S1600536807066561
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author Portalone, Gustavo
Colapietro, Marcello
author_facet Portalone, Gustavo
Colapietro, Marcello
author_sort Portalone, Gustavo
collection PubMed
description In the title compound (alternative name: pyridine-3-carbo­hydrazide, C(6)H(7)N(3)O), the asymmetric unit contains a single mol­ecule. In contrast with nicotinic acid and nicotinamide, the C=O bond is found to be oriented cis with respect to the C(ipso) C N fragment in the pyridine ring. The pyridine ring and the hydrazide group make a dihedral angle of 34.0 (2)°. In the crystal structure, mol­ecules are associated into a three-dimensional framework by a combination of N—H⋯N and three-centre N—H⋯O hydrogen bonds.
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spelling pubmed-29153522010-12-30 Nicotinohydrazide Portalone, Gustavo Colapietro, Marcello Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound (alternative name: pyridine-3-carbo­hydrazide, C(6)H(7)N(3)O), the asymmetric unit contains a single mol­ecule. In contrast with nicotinic acid and nicotinamide, the C=O bond is found to be oriented cis with respect to the C(ipso) C N fragment in the pyridine ring. The pyridine ring and the hydrazide group make a dihedral angle of 34.0 (2)°. In the crystal structure, mol­ecules are associated into a three-dimensional framework by a combination of N—H⋯N and three-centre N—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915352/ /pubmed/21200868 http://dx.doi.org/10.1107/S1600536807066561 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Portalone, Gustavo
Colapietro, Marcello
Nicotinohydrazide
title Nicotinohydrazide
title_full Nicotinohydrazide
title_fullStr Nicotinohydrazide
title_full_unstemmed Nicotinohydrazide
title_short Nicotinohydrazide
title_sort nicotinohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915352/
https://www.ncbi.nlm.nih.gov/pubmed/21200868
http://dx.doi.org/10.1107/S1600536807066561
work_keys_str_mv AT portalonegustavo nicotinohydrazide
AT colapietromarcello nicotinohydrazide

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