Dimethyl­ammonium bis­(3-oxidonaphthalene-2-carboxyl­ato)borate hemihydrate

The title compound, C(2)H(8)N(+)·C(22)H(12)BO(6) (−)·0.5H(2)O, was synthesized under atmospheric conditions in the presence of dimethyl­formamide acting as a template. The structure is composed of [NH(2)(CH(3))(2)](+) cations, bis­(3-oxidonaphthalene-2-carboxyl­ato)borate anions and water mol­ecules...

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Detalles Bibliográficos
Autores principales: Tombul, Mustafa, Güven, Kutalmış, Svoboda, Ingrid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915356/
https://www.ncbi.nlm.nih.gov/pubmed/21200872
http://dx.doi.org/10.1107/S1600536807066810
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author Tombul, Mustafa
Güven, Kutalmış
Svoboda, Ingrid
author_facet Tombul, Mustafa
Güven, Kutalmış
Svoboda, Ingrid
author_sort Tombul, Mustafa
collection PubMed
description The title compound, C(2)H(8)N(+)·C(22)H(12)BO(6) (−)·0.5H(2)O, was synthesized under atmospheric conditions in the presence of dimethyl­formamide acting as a template. The structure is composed of [NH(2)(CH(3))(2)](+) cations, bis­(3-oxidonaphthalene-2-carboxyl­ato)borate anions and water mol­ecules. The water molecule lies on a twofold rotation axis. The stabilization of the crystal structure comes from electrostatic inter­actions and is assisted by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds between the layers.
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spelling pubmed-29153562010-12-30 Dimethyl­ammonium bis­(3-oxidonaphthalene-2-carboxyl­ato)borate hemihydrate Tombul, Mustafa Güven, Kutalmış Svoboda, Ingrid Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(2)H(8)N(+)·C(22)H(12)BO(6) (−)·0.5H(2)O, was synthesized under atmospheric conditions in the presence of dimethyl­formamide acting as a template. The structure is composed of [NH(2)(CH(3))(2)](+) cations, bis­(3-oxidonaphthalene-2-carboxyl­ato)borate anions and water mol­ecules. The water molecule lies on a twofold rotation axis. The stabilization of the crystal structure comes from electrostatic inter­actions and is assisted by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds between the layers. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915356/ /pubmed/21200872 http://dx.doi.org/10.1107/S1600536807066810 Text en © Tombul et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tombul, Mustafa
Güven, Kutalmış
Svoboda, Ingrid
Dimethyl­ammonium bis­(3-oxidonaphthalene-2-carboxyl­ato)borate hemihydrate
title Dimethyl­ammonium bis­(3-oxidonaphthalene-2-carboxyl­ato)borate hemihydrate
title_full Dimethyl­ammonium bis­(3-oxidonaphthalene-2-carboxyl­ato)borate hemihydrate
title_fullStr Dimethyl­ammonium bis­(3-oxidonaphthalene-2-carboxyl­ato)borate hemihydrate
title_full_unstemmed Dimethyl­ammonium bis­(3-oxidonaphthalene-2-carboxyl­ato)borate hemihydrate
title_short Dimethyl­ammonium bis­(3-oxidonaphthalene-2-carboxyl­ato)borate hemihydrate
title_sort dimethyl­ammonium bis­(3-oxidonaphthalene-2-carboxyl­ato)borate hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915356/
https://www.ncbi.nlm.nih.gov/pubmed/21200872
http://dx.doi.org/10.1107/S1600536807066810
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AT svobodaingrid dimethylammoniumbis3oxidonaphthalene2carboxylatoboratehemihydrate

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