S-2-(Adamant-1-yl)-4-methyl­phenyl N,N-dimethyl­thio­carbamate

The title compound, C(20)H(27)NOS, was obtained from the corresponding O-thio­carbamate. The structure features a C=O bond distance of 1.209 (2) Å and an sp (3)-hybridized S atom [C—S—C = 101.66 (1)°]. The steric bulk of the 1-adamantyl substituent on the 2-position of the aromatic ring is reflected...

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Detalles Bibliográficos
Autores principales: Huerta, Raúl, Castillo, Ivan, Hernández-Ortega, Simón
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915366/
https://www.ncbi.nlm.nih.gov/pubmed/21200884
http://dx.doi.org/10.1107/S1600536807066603
Descripción
Sumario:The title compound, C(20)H(27)NOS, was obtained from the corresponding O-thio­carbamate. The structure features a C=O bond distance of 1.209 (2) Å and an sp (3)-hybridized S atom [C—S—C = 101.66 (1)°]. The steric bulk of the 1-adamantyl substituent on the 2-position of the aromatic ring is reflected in the S—C—C—C torsion angle [−7.5 (3)°].

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