S-2-(Adamant-1-yl)-4-methyl­phenyl N,N-dimethyl­thio­carbamate

The title compound, C(20)H(27)NOS, was obtained from the corresponding O-thio­carbamate. The structure features a C=O bond distance of 1.209 (2) Å and an sp (3)-hybridized S atom [C—S—C = 101.66 (1)°]. The steric bulk of the 1-adamantyl substituent on the 2-position of the aromatic ring is reflected...

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Detalles Bibliográficos
Autores principales: Huerta, Raúl, Castillo, Ivan, Hernández-Ortega, Simón
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915366/
https://www.ncbi.nlm.nih.gov/pubmed/21200884
http://dx.doi.org/10.1107/S1600536807066603
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author Huerta, Raúl
Castillo, Ivan
Hernández-Ortega, Simón
author_facet Huerta, Raúl
Castillo, Ivan
Hernández-Ortega, Simón
author_sort Huerta, Raúl
collection PubMed
description The title compound, C(20)H(27)NOS, was obtained from the corresponding O-thio­carbamate. The structure features a C=O bond distance of 1.209 (2) Å and an sp (3)-hybridized S atom [C—S—C = 101.66 (1)°]. The steric bulk of the 1-adamantyl substituent on the 2-position of the aromatic ring is reflected in the S—C—C—C torsion angle [−7.5 (3)°].
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spelling pubmed-29153662010-12-30 S-2-(Adamant-1-yl)-4-methyl­phenyl N,N-dimethyl­thio­carbamate Huerta, Raúl Castillo, Ivan Hernández-Ortega, Simón Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(27)NOS, was obtained from the corresponding O-thio­carbamate. The structure features a C=O bond distance of 1.209 (2) Å and an sp (3)-hybridized S atom [C—S—C = 101.66 (1)°]. The steric bulk of the 1-adamantyl substituent on the 2-position of the aromatic ring is reflected in the S—C—C—C torsion angle [−7.5 (3)°]. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915366/ /pubmed/21200884 http://dx.doi.org/10.1107/S1600536807066603 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Huerta, Raúl
Castillo, Ivan
Hernández-Ortega, Simón
S-2-(Adamant-1-yl)-4-methyl­phenyl N,N-dimethyl­thio­carbamate
title S-2-(Adamant-1-yl)-4-methyl­phenyl N,N-dimethyl­thio­carbamate
title_full S-2-(Adamant-1-yl)-4-methyl­phenyl N,N-dimethyl­thio­carbamate
title_fullStr S-2-(Adamant-1-yl)-4-methyl­phenyl N,N-dimethyl­thio­carbamate
title_full_unstemmed S-2-(Adamant-1-yl)-4-methyl­phenyl N,N-dimethyl­thio­carbamate
title_short S-2-(Adamant-1-yl)-4-methyl­phenyl N,N-dimethyl­thio­carbamate
title_sort s-2-(adamant-1-yl)-4-methyl­phenyl n,n-dimethyl­thio­carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915366/
https://www.ncbi.nlm.nih.gov/pubmed/21200884
http://dx.doi.org/10.1107/S1600536807066603
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AT hernandezortegasimon s2adamant1yl4methylphenylnndimethylthiocarbamate

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