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1,2-Bis(phenylphosphoryl)ethane
The geometric parameters of the molecule of the title compound, C(14)H(16)O(2)P(2), are in the usual ranges. It is a meso compound with the two chiral P atoms having opposite configurations. The P—CH(2)—CH(2)—P chain adopts a trans conformation [torsion angle −178.59 (17)°]. The P=O bonds are almos...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915368/ https://www.ncbi.nlm.nih.gov/pubmed/21200886 http://dx.doi.org/10.1107/S160053680705739X |
Sumario: | The geometric parameters of the molecule of the title compound, C(14)H(16)O(2)P(2), are in the usual ranges. It is a meso compound with the two chiral P atoms having opposite configurations. The P—CH(2)—CH(2)—P chain adopts a trans conformation [torsion angle −178.59 (17)°]. The P=O bonds are almost coplanar with the adjacent phenyl ring [torsion angles = 3.8 (3) and 0.3 (3)°]. Whereas one of them is synclinal [torsion angle = −59.0 (2)°] to the central C—C bond, the other is anticlinal [torsion angle = 56.6 (2)°] to the central C—C bond. The dihedral angle between the two phenyl rings is 5.2 (3)°. The molecules are linked by weak C—H⋯O hydrogen bonds. They crystallize in rows running along the c axis. |
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