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1,2-Bis(phenylphosphoryl)ethane
The geometric parameters of the molecule of the title compound, C(14)H(16)O(2)P(2), are in the usual ranges. It is a meso compound with the two chiral P atoms having opposite configurations. The P—CH(2)—CH(2)—P chain adopts a trans conformation [torsion angle −178.59 (17)°]. The P=O bonds are almos...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915368/ https://www.ncbi.nlm.nih.gov/pubmed/21200886 http://dx.doi.org/10.1107/S160053680705739X |
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author | Dornhaus, Franz Lerner, Hans-Wolfram Bolte, Michael |
author_facet | Dornhaus, Franz Lerner, Hans-Wolfram Bolte, Michael |
author_sort | Dornhaus, Franz |
collection | PubMed |
description | The geometric parameters of the molecule of the title compound, C(14)H(16)O(2)P(2), are in the usual ranges. It is a meso compound with the two chiral P atoms having opposite configurations. The P—CH(2)—CH(2)—P chain adopts a trans conformation [torsion angle −178.59 (17)°]. The P=O bonds are almost coplanar with the adjacent phenyl ring [torsion angles = 3.8 (3) and 0.3 (3)°]. Whereas one of them is synclinal [torsion angle = −59.0 (2)°] to the central C—C bond, the other is anticlinal [torsion angle = 56.6 (2)°] to the central C—C bond. The dihedral angle between the two phenyl rings is 5.2 (3)°. The molecules are linked by weak C—H⋯O hydrogen bonds. They crystallize in rows running along the c axis. |
format | Text |
id | pubmed-2915368 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29153682010-12-30 1,2-Bis(phenylphosphoryl)ethane Dornhaus, Franz Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers The geometric parameters of the molecule of the title compound, C(14)H(16)O(2)P(2), are in the usual ranges. It is a meso compound with the two chiral P atoms having opposite configurations. The P—CH(2)—CH(2)—P chain adopts a trans conformation [torsion angle −178.59 (17)°]. The P=O bonds are almost coplanar with the adjacent phenyl ring [torsion angles = 3.8 (3) and 0.3 (3)°]. Whereas one of them is synclinal [torsion angle = −59.0 (2)°] to the central C—C bond, the other is anticlinal [torsion angle = 56.6 (2)°] to the central C—C bond. The dihedral angle between the two phenyl rings is 5.2 (3)°. The molecules are linked by weak C—H⋯O hydrogen bonds. They crystallize in rows running along the c axis. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915368/ /pubmed/21200886 http://dx.doi.org/10.1107/S160053680705739X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Organic Papers Dornhaus, Franz Lerner, Hans-Wolfram Bolte, Michael 1,2-Bis(phenylphosphoryl)ethane |
title | 1,2-Bis(phenylphosphoryl)ethane |
title_full | 1,2-Bis(phenylphosphoryl)ethane |
title_fullStr | 1,2-Bis(phenylphosphoryl)ethane |
title_full_unstemmed | 1,2-Bis(phenylphosphoryl)ethane |
title_short | 1,2-Bis(phenylphosphoryl)ethane |
title_sort | 1,2-bis(phenylphosphoryl)ethane |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915368/ https://www.ncbi.nlm.nih.gov/pubmed/21200886 http://dx.doi.org/10.1107/S160053680705739X |
work_keys_str_mv | AT dornhausfranz 12bisphenylphosphorylethane AT lernerhanswolfram 12bisphenylphosphorylethane AT boltemichael 12bisphenylphosphorylethane |