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(R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate
In the crystal structure of the title compound, C(43)H(34)N(3)O(5) (+)·C(6)H(2)N(3)O(7) (−)·C(3)H(6)O, the large dimension and shape of the cation are responsible for the elongation of the orthorhombic unit cell. The ions and acetone molecules are linked together by a system of hydrogen bonds inv...
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915369/ https://www.ncbi.nlm.nih.gov/pubmed/21200887 http://dx.doi.org/10.1107/S160053680706669X |
Sumario: | In the crystal structure of the title compound, C(43)H(34)N(3)O(5) (+)·C(6)H(2)N(3)O(7) (−)·C(3)H(6)O, the large dimension and shape of the cation are responsible for the elongation of the orthorhombic unit cell. The ions and acetone molecules are linked together by a system of hydrogen bonds involving an intermolecular hydrogen bond between one N atom of the cation and the O atom of acetone and two intermolecular hydrogen bonds between the cation N atoms and the O atoms of the picrate anion. No intramolecular hydrogen bonds exist in the structure. The dihedral angle between the two naphthalene ring systems is 76.16 (13)°. The chiral C atom has a known R configuration, but this cannot be confirmed from this X-ray analysis. |
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