(R)-2-{2-[(S)-(2′-Benzo­yloxy-1,1′-binaphthyl-2-yl)oxycarbonyl­amino]-3-phenylpropanamido­meth­yl}pyridinium picrate acetone solvate

In the crystal structure of the title compound, C(43)H(34)N(3)O(5) (+)·C(6)H(2)N(3)O(7) (−)·C(3)H(6)O, the large dimension and shape of the cation are responsible for the elongation of the ortho­rhom­bic unit cell. The ions and acetone mol­ecules are linked together by a system of hydrogen bonds inv...

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Autores principales: Streinz, Ludvík, Hartvich, Petr, Ondráček, Jan, Šimek, Petr, Fejfarová, Karla, Dušek, Michal
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915369/
https://www.ncbi.nlm.nih.gov/pubmed/21200887
http://dx.doi.org/10.1107/S160053680706669X
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author Streinz, Ludvík
Hartvich, Petr
Ondráček, Jan
Šimek, Petr
Fejfarová, Karla
Dušek, Michal
author_facet Streinz, Ludvík
Hartvich, Petr
Ondráček, Jan
Šimek, Petr
Fejfarová, Karla
Dušek, Michal
author_sort Streinz, Ludvík
collection PubMed
description In the crystal structure of the title compound, C(43)H(34)N(3)O(5) (+)·C(6)H(2)N(3)O(7) (−)·C(3)H(6)O, the large dimension and shape of the cation are responsible for the elongation of the ortho­rhom­bic unit cell. The ions and acetone mol­ecules are linked together by a system of hydrogen bonds involving an inter­molecular hydrogen bond between one N atom of the cation and the O atom of acetone and two inter­molecular hydrogen bonds between the cation N atoms and the O atoms of the picrate anion. No intra­molecular hydrogen bonds exist in the structure. The dihedral angle between the two naphthalene ring systems is 76.16 (13)°. The chiral C atom has a known R configuration, but this cannot be confirmed from this X-ray analysis.
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spelling pubmed-29153692010-12-30 (R)-2-{2-[(S)-(2′-Benzo­yloxy-1,1′-binaphthyl-2-yl)oxycarbonyl­amino]-3-phenylpropanamido­meth­yl}pyridinium picrate acetone solvate Streinz, Ludvík Hartvich, Petr Ondráček, Jan Šimek, Petr Fejfarová, Karla Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(43)H(34)N(3)O(5) (+)·C(6)H(2)N(3)O(7) (−)·C(3)H(6)O, the large dimension and shape of the cation are responsible for the elongation of the ortho­rhom­bic unit cell. The ions and acetone mol­ecules are linked together by a system of hydrogen bonds involving an inter­molecular hydrogen bond between one N atom of the cation and the O atom of acetone and two inter­molecular hydrogen bonds between the cation N atoms and the O atoms of the picrate anion. No intra­molecular hydrogen bonds exist in the structure. The dihedral angle between the two naphthalene ring systems is 76.16 (13)°. The chiral C atom has a known R configuration, but this cannot be confirmed from this X-ray analysis. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915369/ /pubmed/21200887 http://dx.doi.org/10.1107/S160053680706669X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Streinz, Ludvík
Hartvich, Petr
Ondráček, Jan
Šimek, Petr
Fejfarová, Karla
Dušek, Michal
(R)-2-{2-[(S)-(2′-Benzo­yloxy-1,1′-binaphthyl-2-yl)oxycarbonyl­amino]-3-phenylpropanamido­meth­yl}pyridinium picrate acetone solvate
title (R)-2-{2-[(S)-(2′-Benzo­yloxy-1,1′-binaphthyl-2-yl)oxycarbonyl­amino]-3-phenylpropanamido­meth­yl}pyridinium picrate acetone solvate
title_full (R)-2-{2-[(S)-(2′-Benzo­yloxy-1,1′-binaphthyl-2-yl)oxycarbonyl­amino]-3-phenylpropanamido­meth­yl}pyridinium picrate acetone solvate
title_fullStr (R)-2-{2-[(S)-(2′-Benzo­yloxy-1,1′-binaphthyl-2-yl)oxycarbonyl­amino]-3-phenylpropanamido­meth­yl}pyridinium picrate acetone solvate
title_full_unstemmed (R)-2-{2-[(S)-(2′-Benzo­yloxy-1,1′-binaphthyl-2-yl)oxycarbonyl­amino]-3-phenylpropanamido­meth­yl}pyridinium picrate acetone solvate
title_short (R)-2-{2-[(S)-(2′-Benzo­yloxy-1,1′-binaphthyl-2-yl)oxycarbonyl­amino]-3-phenylpropanamido­meth­yl}pyridinium picrate acetone solvate
title_sort (r)-2-{2-[(s)-(2′-benzo­yloxy-1,1′-binaphthyl-2-yl)oxycarbonyl­amino]-3-phenylpropanamido­meth­yl}pyridinium picrate acetone solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915369/
https://www.ncbi.nlm.nih.gov/pubmed/21200887
http://dx.doi.org/10.1107/S160053680706669X
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