2-(Methoxy­meth­oxy)-1-(4-oxobicyclo­[3.1.0]hexan-1-yl)ethyl 4-nitro­benzoate

In the title compound, C(17)H(19)NO(7), the cyclo­pentane ring is in an envelope conformation in which the methyl­ene group forming the flap is cis to the cyclo­propane group. The relative configuration between the 4-nitro­benzo­yloxy substituent on the side chain and the cyclo­propane ring is trans...

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Detalles Bibliográficos
Autores principales: Li, Jing, Lowary, Todd L., Ferguson, Michael J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915371/
https://www.ncbi.nlm.nih.gov/pubmed/21200889
http://dx.doi.org/10.1107/S160053680706686X
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author Li, Jing
Lowary, Todd L.
Ferguson, Michael J.
author_facet Li, Jing
Lowary, Todd L.
Ferguson, Michael J.
author_sort Li, Jing
collection PubMed
description In the title compound, C(17)H(19)NO(7), the cyclo­pentane ring is in an envelope conformation in which the methyl­ene group forming the flap is cis to the cyclo­propane group. The relative configuration between the 4-nitro­benzo­yloxy substituent on the side chain and the cyclo­propane ring is trans and the methoxy­lmethyl group adopts the expected conformation in which the two O atoms are gauche to one another.
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spelling pubmed-29153712010-12-30 2-(Methoxy­meth­oxy)-1-(4-oxobicyclo­[3.1.0]hexan-1-yl)ethyl 4-nitro­benzoate Li, Jing Lowary, Todd L. Ferguson, Michael J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(19)NO(7), the cyclo­pentane ring is in an envelope conformation in which the methyl­ene group forming the flap is cis to the cyclo­propane group. The relative configuration between the 4-nitro­benzo­yloxy substituent on the side chain and the cyclo­propane ring is trans and the methoxy­lmethyl group adopts the expected conformation in which the two O atoms are gauche to one another. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915371/ /pubmed/21200889 http://dx.doi.org/10.1107/S160053680706686X Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Jing
Lowary, Todd L.
Ferguson, Michael J.
2-(Methoxy­meth­oxy)-1-(4-oxobicyclo­[3.1.0]hexan-1-yl)ethyl 4-nitro­benzoate
title 2-(Methoxy­meth­oxy)-1-(4-oxobicyclo­[3.1.0]hexan-1-yl)ethyl 4-nitro­benzoate
title_full 2-(Methoxy­meth­oxy)-1-(4-oxobicyclo­[3.1.0]hexan-1-yl)ethyl 4-nitro­benzoate
title_fullStr 2-(Methoxy­meth­oxy)-1-(4-oxobicyclo­[3.1.0]hexan-1-yl)ethyl 4-nitro­benzoate
title_full_unstemmed 2-(Methoxy­meth­oxy)-1-(4-oxobicyclo­[3.1.0]hexan-1-yl)ethyl 4-nitro­benzoate
title_short 2-(Methoxy­meth­oxy)-1-(4-oxobicyclo­[3.1.0]hexan-1-yl)ethyl 4-nitro­benzoate
title_sort 2-(methoxy­meth­oxy)-1-(4-oxobicyclo­[3.1.0]hexan-1-yl)ethyl 4-nitro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915371/
https://www.ncbi.nlm.nih.gov/pubmed/21200889
http://dx.doi.org/10.1107/S160053680706686X
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AT lowarytoddl 2methoxymethoxy14oxobicyclo310hexan1ylethyl4nitrobenzoate
AT fergusonmichaelj 2methoxymethoxy14oxobicyclo310hexan1ylethyl4nitrobenzoate

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