N-Benzoyl-N′,N′′-diphenyl­guanidinium chloride

In the title compound, C(20)H(18)N(3)O(+)·Cl(−), the orientation of the aromatic rings around the planar CN(3) (+) unit produces steric hindrance. As a consequence of this particular orientation of the guanidinium cation, hydrogen bonding is restricted to N—H⋯Cl and intra­molecular N—H⋯O hydrogen bo...

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Autores principales: Murtaza, Ghulam, Said, Muhammad, Khawar Rauf, M., Masahiro, Ebihara, Badshah, Amin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915374/
https://www.ncbi.nlm.nih.gov/pubmed/21200894
http://dx.doi.org/10.1107/S1600536807065166
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author Murtaza, Ghulam
Said, Muhammad
Khawar Rauf, M.
Masahiro, Ebihara
Badshah, Amin
author_facet Murtaza, Ghulam
Said, Muhammad
Khawar Rauf, M.
Masahiro, Ebihara
Badshah, Amin
author_sort Murtaza, Ghulam
collection PubMed
description In the title compound, C(20)H(18)N(3)O(+)·Cl(−), the orientation of the aromatic rings around the planar CN(3) (+) unit produces steric hindrance. As a consequence of this particular orientation of the guanidinium cation, hydrogen bonding is restricted to N—H⋯Cl and intra­molecular N—H⋯O hydrogen bonds within the discrete unit. The guanidinium and carbonyl groups are coplanar as a result of the six-membered ring formed by the N—H⋯O intra­molecular hydrogen bond. The dihedral angles between the guanidinium plane and the two phenyl rings are 62.31 (8) and 64.24 (8)°.
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spelling pubmed-29153742010-12-30 N-Benzoyl-N′,N′′-diphenyl­guanidinium chloride Murtaza, Ghulam Said, Muhammad Khawar Rauf, M. Masahiro, Ebihara Badshah, Amin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)N(3)O(+)·Cl(−), the orientation of the aromatic rings around the planar CN(3) (+) unit produces steric hindrance. As a consequence of this particular orientation of the guanidinium cation, hydrogen bonding is restricted to N—H⋯Cl and intra­molecular N—H⋯O hydrogen bonds within the discrete unit. The guanidinium and carbonyl groups are coplanar as a result of the six-membered ring formed by the N—H⋯O intra­molecular hydrogen bond. The dihedral angles between the guanidinium plane and the two phenyl rings are 62.31 (8) and 64.24 (8)°. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915374/ /pubmed/21200894 http://dx.doi.org/10.1107/S1600536807065166 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Murtaza, Ghulam
Said, Muhammad
Khawar Rauf, M.
Masahiro, Ebihara
Badshah, Amin
N-Benzoyl-N′,N′′-diphenyl­guanidinium chloride
title N-Benzoyl-N′,N′′-diphenyl­guanidinium chloride
title_full N-Benzoyl-N′,N′′-diphenyl­guanidinium chloride
title_fullStr N-Benzoyl-N′,N′′-diphenyl­guanidinium chloride
title_full_unstemmed N-Benzoyl-N′,N′′-diphenyl­guanidinium chloride
title_short N-Benzoyl-N′,N′′-diphenyl­guanidinium chloride
title_sort n-benzoyl-n′,n′′-diphenyl­guanidinium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915374/
https://www.ncbi.nlm.nih.gov/pubmed/21200894
http://dx.doi.org/10.1107/S1600536807065166
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AT khawarraufm nbenzoylnndiphenylguanidiniumchloride
AT masahiroebihara nbenzoylnndiphenylguanidiniumchloride
AT badshahamin nbenzoylnndiphenylguanidiniumchloride

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