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1-Bromo-2,4,6-tricyclohexylbenzene
The title compound, C(24)H(25)Br, packs efficiently in the crystal structure with no solvent-accessible voids and several intermolecular H⋯H contacts approximating the sum of the van der Waals radii. The molecule is quite crowded, with intramolecular Br⋯H and C⋯H contacts ca 0.38 and 0.30 Å, resp...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915376/ https://www.ncbi.nlm.nih.gov/pubmed/21200896 http://dx.doi.org/10.1107/S1600536807067062 |
Sumario: | The title compound, C(24)H(25)Br, packs efficiently in the crystal structure with no solvent-accessible voids and several intermolecular H⋯H contacts approximating the sum of the van der Waals radii. The molecule is quite crowded, with intramolecular Br⋯H and C⋯H contacts ca 0.38 and 0.30 Å, respectively, less than the sum of the corresponding van der Waals radii. All cyclohexyl rings adopt chair conformations with the ‘seat’ of the chair inclined at approximately 57–81° to the mean plane of the benzene ring, while those ortho to bromine have their centroids displaced in opposite directions from this plane. |
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