(4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methyl­ethen­yl)perhydro­naphthalen-2-one

In the chiral title compound, C(18)H(28)O(3), the two six-membered rings of the perhydronaphthalenone adopt a rigid chair–chair conformation and the five-membered dioxolanyl ring adopts an envelope conformation. The crystal structure is stabilized only by weak inter­actions.

Detalles Bibliográficos
Autores principales: Siegler, Maxime A., Kooijman, Huub, Spek, Anthony L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915378/
https://www.ncbi.nlm.nih.gov/pubmed/21200898
http://dx.doi.org/10.1107/S1600536807067335
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author Siegler, Maxime A.
Kooijman, Huub
Spek, Anthony L.
author_facet Siegler, Maxime A.
Kooijman, Huub
Spek, Anthony L.
author_sort Siegler, Maxime A.
collection PubMed
description In the chiral title compound, C(18)H(28)O(3), the two six-membered rings of the perhydronaphthalenone adopt a rigid chair–chair conformation and the five-membered dioxolanyl ring adopts an envelope conformation. The crystal structure is stabilized only by weak inter­actions.
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spelling pubmed-29153782010-12-30 (4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methyl­ethen­yl)perhydro­naphthalen-2-one Siegler, Maxime A. Kooijman, Huub Spek, Anthony L. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the chiral title compound, C(18)H(28)O(3), the two six-membered rings of the perhydronaphthalenone adopt a rigid chair–chair conformation and the five-membered dioxolanyl ring adopts an envelope conformation. The crystal structure is stabilized only by weak inter­actions. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915378/ /pubmed/21200898 http://dx.doi.org/10.1107/S1600536807067335 Text en © Siegler et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Siegler, Maxime A.
Kooijman, Huub
Spek, Anthony L.
(4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methyl­ethen­yl)perhydro­naphthalen-2-one
title (4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methyl­ethen­yl)perhydro­naphthalen-2-one
title_full (4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methyl­ethen­yl)perhydro­naphthalen-2-one
title_fullStr (4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methyl­ethen­yl)perhydro­naphthalen-2-one
title_full_unstemmed (4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methyl­ethen­yl)perhydro­naphthalen-2-one
title_short (4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methyl­ethen­yl)perhydro­naphthalen-2-one
title_sort (4as,5r,7r,8s,8ar)-8-(1,3-dioxolan-2-yl)-7,8-dimethyl-5-(1-methyl­ethen­yl)perhydro­naphthalen-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915378/
https://www.ncbi.nlm.nih.gov/pubmed/21200898
http://dx.doi.org/10.1107/S1600536807067335
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AT kooijmanhuub 4as5r7r8s8ar813dioxolan2yl78dimethyl51methylethenylperhydronaphthalen2one
AT spekanthonyl 4as5r7r8s8ar813dioxolan2yl78dimethyl51methylethenylperhydronaphthalen2one

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