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Triethyl­ammonium N′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate

In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (−), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°....

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Detalles Bibliográficos
Autores principales: Singh, Mamata, Srivastava, Ajay K., Singh, N. K., Shrivastav, Anuraag, Sharma, R. K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915380/
https://www.ncbi.nlm.nih.gov/pubmed/21200900
http://dx.doi.org/10.1107/S1600536807067037
Descripción
Sumario:In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (−), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O and N—H⋯S hydrogen bonds, while inter­molecular N—H⋯O, N—H⋯N and weak C—H⋯O inter­actions help to stabilize the crystal structure.